An efficient approach to bridged-bicyclic rings via intramolecular diazo ketone insertion

被引：6

作者：

Chen, L ^{[1
]}

Zhang, XQ ^{[1
]}

Schultz, A ^{[1
]}

机构：

[1] Rensselaer Polytech Inst, Dept Chem, Troy, NY 12180 USA

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 26期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(02)00878-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A regioselective intramolecular diazo ketone insertion reaction of chiral cyclohexenones is described. The methodology shows potential utility in the syntheses of bicyclo[4.2.1]nonan-9-one, bicyclo[4.3.1]decan-10-one and cyclooctanoid rings. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：4711 / 4715

页数：5

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