Reactivity of Diruthenium and Dirhodium Analogues of Pentaborane(9): Agostic versus Boratrane Complexes

被引：79

作者：

Anju, R. S. ^{[1
]}

Roy, Dipak Kumar ^{[1
]}

Mondal, Bijan ^{[1
]}

Yuvaraj, K. ^{[1
]}

Arivazhagan, C. ^{[1
]}

Saha, Koushik ^{[1
]}

Varghese, Babu ^{[2
]}

Ghosh, Sundargopal ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India

[2] Indian Inst Technol, SAIF, Madras 600036, Tamil Nadu, India

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 11期

关键词：

agostic boranes; sigma-boranes; boratranes; rhodium; ruthenium; TRANSITION-METAL-COMPLEXES; BORANE SIGMA-COMPLEXES; METALLABORANE GEOMETRIES; COORDINATION; CHEMISTRY; PHOSPHINE; BOND; DEHYDROGENATION; AMINOBORANE; RUTHENIUM;

D O I：

10.1002/anie.201310416

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of novel Cp*-based (Cp*=eta(5)-C5Me5) agostic, bis(sigma-borate), and boratrane complexes have been synthesized from diruthenium and dirhodium analogues of pentaborane(9). The synthesis and structural characterization of the first neutral ruthenadiborane(6) analogue are also reported. This new route offers a very efficient method for the isolation of bis(sigma-borate) and agostic complexes from diruthe-napentaborane(9).

引用

页码：2873 / 2877

页数：5

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