Cost-effective dopant-free star-shaped oligo-aryl amines for high performance perovskite solar cells

被引：38

作者：

Feng, Jun-Ying ^{[1
,4
]}

Lai, Kuan-Wen ^{[2
,3
]}

Shiue, Yuan-Shin ^{[1
]}

Singh, Ashutosh ^{[1
]}

Kumar, CH. Pavan ^{[1
]}

Li, Chun-Ting ^{[1
]}

Wu, Wen-Ti ^{[1
]}

Lin, Jiann T. ^{[1
]}

Chu, Chih-Wei ^{[2
]}

Chang, Chien-Cheng ^{[3
]}

Su, Chao-chin ^{[4
]}

机构：

[1] Acad Sinica, Inst Chem, 115 Nankang, Taipei, Taiwan

[2] Acad Sinica, Res Ctr Appl Sci, 115 Nankang, Taipei, Taiwan

[3] Natl Taiwan Univ, Inst Appl Mech, Taipei, Taiwan

[4] Natl Taipei Univ Technol, Dept Mol Sci & Engn, Taipei 10608, Taiwan

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2019年 / 7卷 / 23期

关键词：

HOLE-TRANSPORTING MATERIAL; MOLECULAR MATERIALS; V HYSTERESIS; EFFICIENT; DYE; PHTHALOCYANINE; ELECTRON; DESIGN; CARBON; CORE;

D O I：

10.1039/c9ta01278h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cost effective imidazole-based star-shaped oligo(arylamines) were easily prepared in good yields via the reaction of one precursor containing two or more aldehydes with a dione compound having two arylamines. High performance perovskite (MAPbI(3)) solar cells with a conventional cell configuration were fabricated using these compounds as dopant-free hole transport materials. The best solar-to-electricity conversion efficiency reached similar to 17.5%, which surpassed that based on LiTFSI/t-BP doped spiro-OMeTAD. The cell also exhibited much better temporal stability than the standard cell of LiTFSI/t-BP doped spiro-OMeTAD, as no hydrophilic dopants are needed.

引用

页码：14209 / 14221

页数：13

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