Synthesis, structure and reactivity of lanthanocene complexes

被引：0
作者：
Qian, CT
Zhu, CJ
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
[2] Nanjing Univ, Dept Chem, Nanjing 210093, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2002年 / 20卷 / 06期
关键词：
lanthanocene complex; crystal structure; cyclopentadienyl ligand; indenyl ligand; bridging ligand; reduction; polymerization;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A variety of lanthanocene complexes, e.g. chlorides, hydrocarbyls, amides, hydrides and divalent derivatives, were synthesized by using a series of designed cyclopentadienyl, indenyl and fluorenyl ligands with ring bridges or dornor-functionalized sidearms. X-Ray crystallographic analyses reveal the formation of intramolecular coordination bonds between central metals and heteroatoms (O, N) in sidearms or bridging chains. Some applications of these complexes are also discussed in this account.
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页码：519 / 535
页数：17
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