High-yield synthesis of poly(m-phenylenediamine) hollow nanostructures by a diethanolamine-assisted method and their enhanced ability for Ag+ adsorption

被引:16
作者
Su, Zhen [1 ]
Zhang, Liyuan [1 ]
Chai, Liyuan [1 ,2 ]
Wang, Haiying [1 ,2 ]
Yu, Wanting [1 ]
Wang, Ting [1 ]
Yang, Jianxiong [1 ]
机构
[1] Cent South Univ, Sch Met Sci & Engn, Dept Environm Engn, Changsha 410017, Peoples R China
[2] Natl Engn Res Ctr Heavy Met Pollut Control & Trea, Changsha 410017, Peoples R China
基金
中国国家自然科学基金;
关键词
LEAD IONS; OXIDATIVE POLYMERIZATION; M-PHENYLENEDIAMINE; REACTIVE SORPTION; REMOVAL; MICROPARTICLES; NANOPARTICLES; FACILE; POLYPHENYLENEDIAMINE; NANOSPHERES;
D O I
10.1039/c4nj00323c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A diethanolamine-assisted (DEA-assisted) conventional oxidation method was explored to synthesize the hollow nanostructures of poly(m-phenylenediamine) (PmPD) with a high specific surface area. The DEA concentration has a significant influence on the PmPD morphology and a possible formation mechanism has been proposed. The obtained hollow nanostructures show an excellent Ag+ adsorption ability with an adsorbance of 2359.3 mg g(-1), much higher than other reported materials.
引用
收藏
页码:3984 / 3991
页数:8
相关论文
共 42 条
[1]   Aligned carbon nanotube, graphene and graphite oxide thin films via substrate-directed rapid interfacial deposition [J].
D'Arcy, Julio M. ;
Tran, Henry D. ;
Stieg, Adam Z. ;
Gimzewski, James K. ;
Kaner, Richard B. .
NANOSCALE, 2012, 4 (10) :3075-3082
[2]   Graphene-Wrapped Polyaniline Hollow Spheres As Novel Hybrid Electrode Materials for Supercapacitor Applications [J].
Fan, Wei ;
Zhang, Chao ;
Tjiu, Weng Weei ;
Pramoda, Kumari Pallathadka ;
He, Chaobin ;
Liu, Tianxi .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (08) :3382-3391
[3]  
Guo T., 2012, J MAT SCI RES, V1, P25
[4]   Highly efficient adsorbents of poly(o-phenylenediamine) solid and hollow sub-microspheres towards lead ions: A comparative study [J].
Han, J. ;
Dai, J. ;
Guo, R. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 356 (02) :749-756
[5]   Synthesis of poly(o-phenylenediamine) hollow spheres and nanofibers using different oxidizing agents [J].
Han, Jie ;
Song, Genping ;
Guo, Rong .
EUROPEAN POLYMER JOURNAL, 2007, 43 (10) :4229-4235
[6]   One-Pot Surfactantless Route to Polyaniline Hollow Nanospheres with Incontinuous Multicavities and Application for the Removal of Lead Ions from Water [J].
Han, Jie ;
Fang, Ping ;
Dai, Jie ;
Guo, Rong .
LANGMUIR, 2012, 28 (15) :6468-6475
[7]   Rapid and effective adsorption of lead ions on fine poly(phenylenediamine) microparticles [J].
Huang, Mei-Rong ;
Peng, Qian-Yun ;
Li, Xin-Gui .
CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (16) :4341-4350
[8]   Lead-ion potentiometric sensor based on electrically conducting microparticles of sulfonic phenylenediamine copolymer [J].
Huang, Mei-Rong ;
Ding, Yong-Bo ;
Li, Xin-Gui .
ANALYST, 2013, 138 (13) :3820-3829
[9]   Synthesis and strong heavy-metal ion sorption of copolymer microparticles from phenylenediamine and its sulfonate [J].
Huang, Mei-Rong ;
Lu, Hong-Jie ;
Li, Xin-Gui .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (34) :17685-17699
[10]   Lead ion-selective electrodes based on polyphenylenediamine as unique solid ionophores [J].
Huang, Mei-Rong ;
Rao, Xue-Wu ;
Li, Xin-Gui ;
Ding, Yong-Bo .
TALANTA, 2011, 85 (03) :1575-1584