Phosphole-containing hybrid calixpyrroles: New multifunctional macrocyclic ligands for platinum(II) ions

被引：26
|
作者：
Matano, Yoshihiro [1 ]
Nakabuchi, Takashi [1 ]
Miyajima, Tooru [1 ]
Imahori, Hiroshi [1 ]
机构：
[1] Kyoto Univ, Dept Mol Engn, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan
来源：
ORGANOMETALLICS | 2006年 / 25卷 / 13期
关键词：
D O I：
10.1021/om060300a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Phosphole-containing hybrid calixpyrroles have been prepared by acid-promoted condensation reactions. sigma(3)-Calix[ 1] phosphole[1] thiophene[2] pyrrole reacts with PtCl2(COD) to afford an unusual type of macrocyclic Pt(II)- monophosphine complex bearing a eta(3)-cyclooctadienyl ligand, in which the phosphole and pyrrole units bind the Pt-Cl moiety through cooperative, noncovalent bonding interactions.
引用
收藏
页码：3105 / 3107
页数：3
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