Organometallic synthesis in room-temperature chloroaluminate(III) ionic liquids

被引：0
|
作者：
Crofts, D [1 ]
Dyson, PJ [1 ]
Sanderson, KM [1 ]
Srinivasan, N [1 ]
Welton, T [1 ]
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
来源：
ADVANCES IN MOLTEN SALTS: FROM STRUCTURAL ASPECT TO WASTE PROCESSING | 1999年
关键词：
ionic liquids; chloroaluminate(III); Friedel-Crafts; cyclophanes; metallocenes;
D O I：
暂无
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The ionic liquid system [bmim]Cl-AlCl3 ([bmim](+) = 1-butyl-3-methylimidazolium cation) is used as a combination of solvent and Lewis acid catalyst in a number of carbon-carbon and metal-carbon bond-forming reactions. Friedel-Crafts reactions of ferrocene and ruthenocene, as a function of acidity of the ionic liquid are reported. The formation of cationic metal-arene complexes under similar conditions is also reported.
引用
收藏
页码：624 / 633
页数：4
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