Organometallic synthesis in room-temperature chloroaluminate(III) ionic liquids

被引：0

作者：

Crofts, D ^{[1
]}

Dyson, PJ ^{[1
]}

Sanderson, KM ^{[1
]}

Srinivasan, N ^{[1
]}

Welton, T ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

ADVANCES IN MOLTEN SALTS: FROM STRUCTURAL ASPECT TO WASTE PROCESSING | 1999年

关键词：

ionic liquids; chloroaluminate(III); Friedel-Crafts; cyclophanes; metallocenes;

D O I：

暂无

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The ionic liquid system [bmim]Cl-AlCl3 ([bmim](+) = 1-butyl-3-methylimidazolium cation) is used as a combination of solvent and Lewis acid catalyst in a number of carbon-carbon and metal-carbon bond-forming reactions. Friedel-Crafts reactions of ferrocene and ruthenocene, as a function of acidity of the ionic liquid are reported. The formation of cationic metal-arene complexes under similar conditions is also reported.

引用

页码：624 / 633

页数：4

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