Electron paramagnetic resonance investigations of ammonia and aniline copper(II) complexes

被引：3
作者：
Labanowska, M [1 ]
Zurowski, KR [1 ]
Bidzinska, E [1 ]
机构：
[1] JAN KOCHANOWSKI UNIV HUMANITIES & SCI, INST CHEM, PL-25020 KIELCE, POLAND
来源：
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1996年 / 115卷
关键词：
ammonia; aniline; copper(II) complexes; EPR; exchange interactions;
D O I：
10.1016/0927-7757(96)03616-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Electron paramagnetic resonance investigations of both ammonia and aniline copper(II) complexes revealed stronger exchange interactions in the CuCl2 . 2NH(3) crystal lattice than in the lattice of the aniline complex. The crystal lattice of CuCl2 . 2NH(3) may be considered as a system of infinite chain links with two halide bridges between adjacent copper atoms and two ammonia ligands in axial positions. In CuCl2 . 2(aniline) the halide bridges are broken, so the interaction between copper ions becomes negligible and the structure of the aniline complex exhibits lower symmetry.
引用
收藏
页码：297 / 301
页数：5
相关论文
共 50 条
  • [21] Electron paramagnetic resonance of switchable copper-nitroxide-based molecular magnets: An indispensable tool for intriguing systems
    Fedin, Matvey V.
    Veber, Sergey L.
    Bagryanskaya, Elena G.
    Ovcharenko, Victor I.
    COORDINATION CHEMISTRY REVIEWS, 2015, 289 : 341 - 356
  • [22] ELECTRON-PARAMAGNETIC-RESONANCE AND POLAROGRAPHY OF COPPER(II)-L-HISTIDINE (1/1) AND COPPER(II)-L-HISTIDINE-IMIDAZOLE (1/1/1) SYSTEMS
    PATEL, RN
    PANDEYA, KB
    SINGH, PK
    BULLETIN OF ELECTROCHEMISTRY, 1995, 11 (05): : 235 - 240
  • [23] Magnetic structure of manganese cluster in photosystem II investigated by electron paramagnetic resonance
    Nagashima, Hiroki
    Asada, Mizue
    Mino, Hiroyuki
    BIOPHYSICS AND PHYSICOBIOLOGY, 2018, 15 : 45 - 50
  • [24] A GUIDE TO ELECTRON-PARAMAGNETIC RESONANCE SPECTROSCOPY OF PHOTOSYSTEM-II MEMBRANES
    MILLER, AF
    BRUDVIG, GW
    BIOCHIMICA ET BIOPHYSICA ACTA, 1991, 1056 (01) : 1 - 18
  • [25] Cyclic voltammetric investigations of copper(II) complexes with various imidazoles in dimethylformamide
    Prasad, J.
    Ukpong, E. J.
    Srivastava, Krishna
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2008, 85 (01) : 32 - 35
  • [26] Biosorption of copper by dried plant leaves studied by electron paramagnetic resonance and infrared spectroscopy
    de Carvalho, RP
    Guedes, KJ
    Pinheiro, MVB
    Krambrock, K
    HYDROMETALLURGY, 2001, 59 (2-3) : 407 - 412
  • [27] Electron paramagnetic resonance spectroscopy in structural-dynamic studies of large protein complexes
    Galazzo, Laura
    Bordignon, Enrica
    PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 2023, 134-135 : 1 - 19
  • [28] Mapping Magnetic Properties and Relaxation in Vanadium(IV) Complexes with Lanthanides by Electron Paramagnetic Resonance
    Kurganskii, Ivan, V
    Bazhina, Evgeniya S.
    Korlyukov, Alexander A.
    Babeshkin, Konstantin A.
    Efimov, Nikolay N.
    Kiskin, Mikhail A.
    Veber, Sergey L.
    Sidorov, Alexey A.
    Eremenko, Igor L.
    Fedin, Matvey, V
    MOLECULES, 2019, 24 (24):
  • [29] Electron paramagnetic resonance and quantitative color investigations of various vacuum heat treated wood species
    Kondratyeva, E. I.
    Safiullin, K. R.
    Motygullin, I. G.
    Klochkov, A. V.
    Tagirov, M. S.
    Kuzmin, V. V.
    MAGNETIC RESONANCE IN SOLIDS, 2015, 17 (02)
  • [30] Probing electronic structures of transition metal complexes using electron paramagnetic resonance spectroscopy
    Ye, Shengfa
    MAGNETIC RESONANCE LETTERS, 2023, 3 (01) : 43 - 60
12345