Synthesis of N-(4′-benzo[15-crown-5])biphenylaminoglyoxime and its complexes with some transition metals

被引:13
|
作者
Karapinar, E [1 ]
Karapinar, N
Özcan, E
机构
[1] Pamukkale Univ, Fac Arts & Sci, Dept Chem, TR-20017 Denizli, Turkey
[2] Pamukkale Univ, Fac Engn, Dept Chem Engn, TR-20017 Denizli, Turkey
[3] Selcuk Univ, Fac Arts & Sci, Dept Chem, TR-42031 Konya, Turkey
关键词
D O I
10.1023/B:RUCO.0000034790.13764.b7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
N'-(4'-Benzo[15-crown-5])biphenylaminoglyoxime (H2L) and sodium chloride salt of N'-(4'-benzo[15-crown-5])biphenylaminoglyoxime (H2L . NaCl) have been prepared from 4-biphenylchloroglyoxime, 4'-aminobenzo[15-crown-5], and sodium bicarbonate and sodium chloride. Nickel(II), cobalt(II), and copper(II) complexes with H2L and H2L . NaCl have a metal-ligand ratio of 1 : 2 and the ligand coordinates through the two N atoms, as do most of the vic-dioximes. Their IR spectra and elemental analyses are given, together with H-1 NMR spectra of the ligands.
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页码:491 / 495
页数:5
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