Emulsion polymerization of styrene using polystyrene-block-poly(ethylene oxide) macromonomers as stabilizers

被引：7
作者：
Gibanel, S
Heroguez, V
Forcada, J
机构：
[1] Univ Basque Country, EHU, Inst Polymer Mat POLYMAT, San Sebastian 20080, Spain
[2] Univ Basque Country, EHU, Fac Ciencias Quim, Dept Quim Aplicada,Grp Ingn Quim, San Sebastian 20080, Spain
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2002年 / 40卷 / 16期
关键词：
macromonomers; surfactants; diblock copolymers; emulsion polymerization;
D O I：
10.1002/pola.10379
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
New diblock macromonomers were used as reactive emulsifiers in the emulsion polymerization of styrene. The nature of the reactive group, the molecular weight, the length of the poly(ethylene oxide) (PEO) block, and the molecular structure of the macromonomer were systematically investigated during this process by analyzing the evolution of the conversion and particle diameters. (C) 2002 Wiley Periodicals, Inc.
引用
收藏
页码：2819 / 2827
页数：9
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