New Bromine Complexing Agents for Bromine based Batteries

被引:44
作者
Lancry, E. [1 ]
Magnes, B. Z. [1 ]
Ben-David, I. [1 ]
Freiberg, M. [1 ]
机构
[1] ICL IP R&D, IL-84101 Beer Sheva, Israel
来源
STATIONARY AND LARGE SCALE ELECTRICAL ENERGY STORAGE 2 | 2013年 / 53卷 / 07期
关键词
ZINC; CELLS;
D O I
10.1149/05307.0107ecst
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Bromine is a very good electro active species, with fast and reversible kinetics. However, it possesses a high vapor pressure and reactivity which require stabilization via complexing agents, which reduce reactivity and vapor pressure without changing its electrochemical properties. Currently, bromide based batteries like the Zinc/Bromine cell, use as Bromide complexing agents, either Methyl Ethyl Morpholinium Bromide (MEM) or Methyl Ethyl Pyrrolidinium Bromide (MEP) or their mixture. Both complexing agents have been well known in the field for about 40 years. A possible drawback of their use as complexing agents for bromine is that they are not always compatible with different bromide chemistries. ICL-IP has developed a family of new effective Bromide complexing agents that are compatible with various bromide based chemistries and applications.
引用
收藏
页码:107 / 115
页数:9
相关论文
共 12 条
[1]   THE KINETICS OF THE ZINC CHLORIDE-CATALYZED BROMINATION OF POLYMETHYLBENZENES IN ACETIC ACID SOLUTION [J].
ANDREWS, LJ ;
KEEFER, RM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (18) :4549-4553
[3]   SELECTION OF QUATERNARY AMMONIUM BROMIDES FOR USE IN ZINC BROMINE CELLS [J].
CATHRO, KJ ;
CEDZYNSKA, K ;
CONSTABLE, DC ;
HOOBIN, PM .
JOURNAL OF POWER SOURCES, 1986, 18 (04) :349-370
[4]   SOME PROPERTIES OF ZINC BROMINE BATTERY ELECTROLYTES [J].
CATHRO, KJ ;
CEDZYNSKA, K ;
CONSTABLE, DC .
JOURNAL OF POWER SOURCES, 1985, 16 (01) :53-63
[5]   PROPERTIES OF MODIFIED ELECTROLYTE FOR ZINC-BROMINE CELLS [J].
CEDZYNSKA, K .
ELECTROCHIMICA ACTA, 1995, 40 (08) :971-976
[6]  
Eidler P., 1997, U.S. Patent No, Patent No. [5,591,538, 5591538]
[7]  
Eustace D.J, 1978, US Patent, Patent No. 4068046
[8]  
Eustace D. J., 1977, [No title captured], Patent No. [4064324, US 4064324]
[9]   BROMINE COMPLEXATION IN ZINC-BROMINE CIRCULATING BATTERIES [J].
EUSTACE, DJ .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (03) :528-532
[10]   In situ-generated zinc bromide-catalyzed α-bromination of alkanones in water [J].
Juneja, Satinder K. ;
Choudhary, Deepak ;
Paul, Satya ;
Gupta, Rajive .
SYNTHETIC COMMUNICATIONS, 2006, 36 (19) :2877-2881