Tailorable Aqueous Dispersion of Single-Walled Carbon Nanotubes Using Tetrachloroperylene-Based Bolaamphiphiles via Noncovalent Modification

被引：23

作者：

Sun, Yan ^{[1
,2
]}

Fu, Wenxin ^{[1
]}

Li, Zhibo ^{[1
]}

Wang, Zhaohui ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China

[2] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Peoples R China

来源：

LANGMUIR | 2014年 / 30卷 / 28期

基金：

中国国家自然科学基金;

关键词：

ELECTRON-TRANSFER; BLOCK-COPOLYMERS; WATER; FUNCTIONALIZATION; SOLUBILIZATION; DERIVATIVES; DESIGN; NANOHYBRIDS; SURFACTANTS; COMPLEXES;

D O I：

10.1021/la502222d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The enhanced dispersing capability of these bolaamphiphiles can be attributed to the large aromatic perylene core. The aqueous dispersion efficiency of single-walled carbon nanotubes (SWCNTs) is investigated by UV-vis absorption, fluorescence emission and Raman spectra, scanning electron microscopy, transmission electron microscopy, and atomic force microscopy. It is found that the tetrachloroperylene backbone moieties could interact with SWCNT via synergistic it it and hydrophobic interactions, and the dispersing properties are closely related to the hydrophilic part of bolaamphiles. This study not only demonstrates tetrachloroperylene derivatives are able to stabilize SWCNTs, but also provides the possibility to understand the structure property relationship between SWCNTs and tetrachloroperylene-based surfactants.

引用

页码：8615 / 8620

页数：6

共 43 条

[1] The Potential of Perylene Bisimide Derivatives for the Solubilization of Carbon Nanotubes and Graphene [J].

Backes, Claudia ;

Hauke, Frank ;

Hirsch, Andreas .

ADVANCED MATERIALS, 2011, 23 (22-23) :2588-2601

[2] Nanotube Surfactant Design: The Versatility of Water-Soluble Perylene Bisimides [J].

Backes, Claudia ;

Schmidt, Cordula D. ;

Rosenlehner, Karin ;

Hauke, Frank ;

Coleman, Jonathan N. ;

Hirsch, Andreas .

ADVANCED MATERIALS, 2010, 22 (07) :788-802

[3] High Population of Individualized SWCNTs through the Adsorption of Water-Soluble Perylenes [J].

Backes, Claudia ;

Schmidt, Cordula D. ;

Hauke, Frank ;

Boettcher, Christoph ;

Hirsch, Andreas .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (06) :2172-2184

[4] Properties of carbon nanotube fibers spun from DNA-stabilized dispersions [J].

Barisci, JN ;

Tahhan, M ;

Wallace, GG ;

Badaire, S ;

Vaugien, T ;

Maugey, M ;

Poulin, P .

ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (02) :133-138

[5] Reversible control of carbon nanotube aggregation for a glucose affinity sensor [J].

Barone, Paul W. ;

Strano, Michael S. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (48) :8138-8141

[6] Carbon nanotubes with covalently linked porphyrin antennae: Photoinduced electron transfer [J].

Baskaran, D ;

Mays, JW ;

Zhang, XP ;

Bratcher, MS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (19) :6916-6917

[7] Noncovalent interactions of molecules with single walled carbon nanotubes [J].

Britz, David A. ;

Khlobystov, Andrei N. .

CHEMICAL SOCIETY REVIEWS, 2006, 35 (07) :637-659

[8] Single-walled carbon nanotube dispersions in poly(ethylene oxide) [J].

Chatterjee, T ;

Yurekli, K ;

Hadjiev, VG ;

Krishnamoorti, R .

ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (11) :1832-1838

[9] Noncovalent functionalization of single-walled carbon nanotubes with water-soluble porphyrins [J].

Chen, JY ;

Collier, CP .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (16) :7605-7609

[10] Light-controlled single-walled carbon nanotube dispersions in aqueous solution [J].

Chen, Senlin ;

Jiang, Yugui ;

Wang, Zhiqiang ;

Zhang, Xi ;

Dai, Liming ;

Smet, Mario .

LANGMUIR, 2008, 24 (17) :9233-9236

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