Metallization of magnetite at high pressures

被引:36
作者
Môri, N
Todo, S
Takeshita, N
Mori, T
Akishige, Y
机构
[1] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan
[2] Saitama Univ, Dept Phys, Urawa, Saitama 3388570, Japan
[3] Joint Res Ctr Atom Technol, Tsukuba, Ibaraki 3040046, Japan
[4] Shimane Univ, Matsue, Shimane 690, Japan
关键词
magnetite; Verwey transition; insulator-metal transition; pressure;
D O I
10.1016/S0921-4526(01)01525-3
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We report on the first finding that an insulator to metal transition (i.e. Verwey transition) of magnetite (Fe3O4) lakes place at absolute zero temperature as a function of pressure. In order to investigate the Verwey transition, we measured the electrical resistivity on two single crystalline samples with distinct oxygen compositions of Fe3O4.002 and Fe3O4.007 at temperatures from 300K down to 3 K under a pressure up to 9 GPa using a cubic anvil apparatus. The Verwey transition temperature of these samples suddenly disappears at a certain critical pressure P-c in between 6 and 8 GPa. We confirmed that a metallic ground state is realized in magnetite under pressure above P-c. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:686 / 690
页数:5
相关论文
共 23 条
[1]  
AKISHIGE Y, 1988, SOLID STATE PHYS, V23, P87
[2]   Charge-ordered insulating state of Fe3O4 from first-principles electronic structure calculations [J].
Anisimov, VI ;
Elfimov, IS ;
Hamada, N ;
Terakura, K .
PHYSICAL REVIEW B, 1996, 54 (07) :4387-4390
[3]   HIGH-RESOLUTION PHOTOEMISSION SPECTROSCOPY OF THE VERWEY TRANSITION IN FE3O4 [J].
CHAINANI, A ;
YOKOYA, T ;
MORIMOTO, T ;
TAKAHASHI, T ;
TODO, S .
PHYSICAL REVIEW B, 1995, 51 (24) :17976-17979
[4]   MULTIPLE ORDERING IN MAGNETITE [J].
CULLEN, JR ;
CALLEN, ER .
PHYSICAL REVIEW B, 1973, 7 (01) :397-402
[5]   STUDY OF 123-K PHASE-TRANSITION OF MAGNETITE BY CRITICAL NEUTRON-SCATTERING [J].
FUJII, Y ;
SHIRANE, G ;
YAMADA, Y .
PHYSICAL REVIEW B, 1975, 11 (05) :2036-2041
[6]   Absence of charge ordering below the Verwey transition temperature in magnetite -: art. no. 054110 [J].
García, J ;
Subías, G ;
Proietti, MG ;
Blasco, J ;
Renevier, H ;
Hodeau, JL ;
Joly, Y .
PHYSICAL REVIEW B, 2001, 63 (05)
[7]  
HONIG JM, 1985, METALLIC NONMETALLIC, P261
[8]   STRUCTURE OF MAGNETITE (FE3O4) BELOW THE VERWEY TRANSITION-TEMPERATURE [J].
IIZUMI, M ;
KOETZLE, TF ;
SHIRANE, G ;
CHIKAZUMI, S ;
MATSUI, M ;
TODO, S .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (AUG) :2121-2133
[9]  
ISHIDA S, 1998, J PHYS SOC JPN, V67, P3125
[10]  
JHRE D, 1985, J PHYS C SOLID STATE, V18, pL647