Double complex [Mn2(C11H13N3O)6(H2O)2][Cr(NH3)2(NCS)4]4: Synthesis and crystal structure

被引：0

作者：

Cherkasova, T. G. ^{[1
]}

Bagryanskaya, I. Yu. ^{[2
,3
]}

Pervukhina, N. V. ^{[4
]}

Vornakov, A. L. ^{[1
]}

Cherkasova, E. V. ^{[1
]}

Kuratieva, N. V. ^{[3
,4
]}

机构：

[1] Kuzbass State Tech Univ, Ul Vesennyaya 28, Kemerovo 650000, Russia

[2] Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia

[3] Novosibirsk Natl Res State Univ, Ul Pirogova 2, Novosibirsk 630090, Russia

[4] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Pr Akad Lavrenteva 3, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 62卷 / 02期

关键词：

CU(II)/CR(III) COMPLEXES; REINECKES SALT; COPPER-POWDER; X-RAY;

D O I：

10.1134/S003602361702005X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Mn-2(C11H13N3O)(6)(H2O)(2)][Cr(NH3)(2)(NCS)(4)](4) (I) has been synthesized by the reaction between MnCl2 center dot H2O, NH4[Cr(NH3)(2)(NCS)(4)] center dot 0.5H(2)O and 4-aminoantipyrine (C11H13N3O) in an aqueous solution, and its structure has been determined by IR spectroscopy and X-ray diffraction. Crystals of complex I are triclinic, space group , Z = 1, a = 13.2378(5) , b = 15.7796(5) , c = 16.7703(6) , alpha = 83.194(2)A degrees, beta = 75.874(2)A degrees, gamma = 66.529(1)A degrees, V = 3115.2(2) (3), and rho(calcd) = 1.407 g/cm(3).

引用

页码：182 / 186

页数：5

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