Catalytic combustion of volatile organic compound over spherical-shaped copper-manganese oxide

被引:52
作者
Ahn, Chi-Woong [1 ,2 ]
You, Young-Woo [1 ]
Heo, Iljeong [1 ]
Hong, Ji Sook [1 ]
Jeon, Jong-Ki [2 ]
Ko, Young-Deok [3 ]
Kim, YoHan [5 ]
Park, Hosik [4 ]
Suh, Jeong-Kwon [1 ]
机构
[1] Korea Res Inst Chem Technol, Carbon Resources Inst, 141 Gajeong Ro, Daejeon 305600, South Korea
[2] Kongju Natl Univ, Dept Chem Engn, 56 Gongju Si, Chungcheongnam Do 314701, South Korea
[3] Puresphere, 105 Shinildong Ro, Daejeon 34324, South Korea
[4] Korea Res Inst Chem Technol, Adv Mat Div, 141 Gajeong Ro, Daejeon 305600, South Korea
[5] Gwangju Inst Sci & Technol, Sch Environm Sci & Engn, 123 Cheomdan Gwagiro, Gwangju 500712, South Korea
关键词
Catalytic combustion; Volatile organic compound; Spherical-shape; Copper manganese oxide; TOTAL OXIDATION; BENZENE OXIDATION; ETHYL-ACETATE; TOLUENE; TEMPERATURE; PERFORMANCE; CO; REMOVAL; VOCS; FORMALDEHYDE;
D O I
10.1016/j.jiec.2016.12.018
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Amorphous spherical-shaped copper-manganese oxide for the catalytic combustion of benzene were successfully obtained by a wet granulation process under different calcination temperatures. The low temperature (400 degrees C) calcined catalysts which showed a larger BET specific surface area, low temperature reducibility, and an amorphous phase were more active for the catalytic combustion of benzene than the high-temperature calcined catalyst which underwent the amorphous to crystalline phase transition. The catalytic activity tests, depending on the operating parameters, suggested that amorphous spherical-shaped copper-manganese oxide have potential applications for remedying VOC pollution. (C) 2016 Published by Elsevier B.V. on behalf of The Korean Society of Industrial and Engineering Chemistry.
引用
收藏
页码:439 / 445
页数:7
相关论文
共 47 条
[1]   Catalytic combustion of volatile organic compounds in binary mixtures over MnOx/Al2O3 catalyst [J].
Aguero, Fabiola N. ;
Barbero, Bibiana P. ;
Gambaro, Luis ;
Cadus, Luis E. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 91 (1-2) :108-112
[2]   Towards industrial use of metal-organic framework: Impact of shaping on the MOF properties [J].
Bazer-Bachi, D. ;
Assie, L. ;
Lecocq, V. ;
Harbuzaru, B. ;
Falk, V. .
POWDER TECHNOLOGY, 2014, 255 :52-59
[3]   A spillover approach to oxidation catalysis over copper and manganese mixed oxides [J].
Buciuman, FC ;
Patcas, F ;
Hahn, T .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 1999, 38 (4-6) :563-569
[4]   Mesoporous Cu-Mn Hopcalite catalyst and its performance in low temperature ethylene combustion in a carbon dioxide stream [J].
Chen, Hong ;
Tong, Xinli ;
Li, Yongdan .
APPLIED CATALYSIS A-GENERAL, 2009, 370 (1-2) :59-65
[5]   VOC oxidation over CuO-CeO2 catalysts prepared by a combustion method [J].
Delimaris, Dimitrios ;
Ioannides, Theophilos .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 89 (1-2) :295-302
[6]   Gas-Phase Total Oxidation of Benzene, Toluene, Ethylbenzene, and Xylenes Using Shape-Selective Manganese Oxide and Copper Manganese Oxide Catalysts [J].
Genuino, Homer C. ;
Dharmarathna, Saminda ;
Njagi, Eric C. ;
Mei, Michael C. ;
Suib, Steven L. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (22) :12066-12078
[7]   VOCs removal from dilute vapour streams by adsorption onto activated carbon [J].
Gironi, F. ;
Piemonte, V. .
CHEMICAL ENGINEERING JOURNAL, 2011, 172 (2-3) :671-677
[8]   Catalytic oxidation of methanol on nanoscale copper oxide and nickel oxide [J].
Gu, Z ;
Hohn, KL .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (01) :30-35
[9]   Removal of volatile organic compounds by cryogenic condensation followed by adsorption [J].
Gupta, VK ;
Verma, N .
CHEMICAL ENGINEERING SCIENCE, 2002, 57 (14) :2679-2696
[10]   Cyclohexane oxidation and carbon deposition over metal oxide catalysts [J].
Hettige, C ;
Mahanama, KRR ;
Dissanayake, DP .
CHEMOSPHERE, 2001, 43 (08) :1079-1083