Easy, Green and Safe Carbonylation Reactions through Zeolite-Catalyzed Carbon Monoxide Production from Formic Acid

被引：29

作者：

Losch, Pit ^{[1
]}

Felten, Anne-Sophie ^{[1
]}

Pale, Patrick ^{[1
]}

机构：

[1] Univ Strasbourg, Inst Chim, Lab Synth React Organ & Catalyse, UMR CNRS 7177, F-67000 Strasbourg, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2015年 / 357卷 / 13期

关键词：

carbonylation; catalysis; cross-coupling; palladium; zeolites; KHAND-TYPE REACTION; ARYL HALIDES; SITU GENERATION; EX-SITU; EFFICIENT; SYSTEM; AMINOCARBONYLATIONS; REACTIVITY; MO(CO)(6); EVOLUTION;

D O I：

10.1002/adsc.201500384

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Zeolites with the right shape and acid site density and strength, such as certain ZSM-5 forms, were able to cleanly decompose formic acid to carbon monoxide (CO), and the latter could be directly used in palladium-catalyzed carbonylation reactions. A simple two-reactor system was designed to produce CO conveniently and then further react this gas in a safe way. The two-reactor system is particularly cheap, easy to set up and use. In addition, the carbonylation conditions without pressure allowed for very efficient CO incorporation, with only 1% of palladium(II) chloride (PdCl2) and Xantphos.

引用

页码：2931 / 2938

页数：8

共 59 条

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