Facile strategy to produce N-doped carbon aerogels derived from seaweed for lithium-ion battery anode

被引:54
作者
Zhang, Junlu [1 ,2 ]
Zhang, Lijie [1 ,2 ]
Yang, Shuanglei [1 ,2 ]
Li, Daohao [1 ,2 ]
Xie, Zhixian [1 ,2 ]
Wang, Bingbing [1 ,3 ]
Xia, Yanzhi [1 ]
Quan, Fengyu [1 ,2 ]
机构
[1] Qingdao Univ, Inst Marine Biobased Mat, Collaborat Innovat Ctr Marine Biomass Fibers Mat, Qingdao 266071, Peoples R China
[2] Qingdao Univ, Coll Mat Sci & Engn, Qingdao 266071, Peoples R China
[3] Yantai Tayho Adv Mat Grp Co Ltd, 9 Heilongjiang Rd, Yantai Edta 264000, Shandong, Peoples R China
关键词
Sodium alginate; N-doped carbon aerogels; Porous structure; Lithium-ion batteries; OXYGEN REDUCTION REACTION; HIGH-PERFORMANCE; CATHODE MATERIAL; GRAPHENE; STORAGE; NANOFIBER; BIOMASS; NANOTUBES; COMPOSITE; CATALYSIS;
D O I
10.1016/j.jallcom.2017.01.082
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Biomass materials as sustainable carbon precursor have attracted great attention in electrochemical energy conversion and storage. Herein we demonstrated a facile strategy to produce N-doped activated carbon aerogels (N-ACAS) with porous structure derived from sodium alginate for lithium-ion batteries (LIBs). Vitally, the porous carbon aerogels with high specific surface area of 2136 m(2) g(-1) and the macro-esoporous structure are observed in the formed N-ACAS. When using N-ACAs as an anode material, formatting the three-dimensional pathway through the N-doping carbon aerogels structure not only provides more connection opportunities for electrolyte and the electrode, but also promotes the charge transfer reaction. Meanwhile, the obtained N-ACAs exhibits a reversible capacity about 550 mAh g(-1) at 1 C (1 C = 372 mA g(-1)) after 300 cycles, considering as appealing anode material with the high specific capacity, good rate capability, and excellent cycling performance for LIBs. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:256 / 261
页数:6
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