Synthesis of Polyhydroxylated Carbocyclic Derivatives with Medium Rings

被引：4

作者：

Osuch-Kwiatkowska, Anna ^{[1
]}

Jarosz, Slawomir ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

来源：

CURRENT ORGANIC CHEMISTRY | 2014年 / 18卷 / 13期

关键词：

Medium ring cyclitols; rearrangement; sugar mimetics; sugars; OLEFIN METATHESIS CATALYSTS; NITRONE-ALKENE CYCLOADDITION; PROTON MAGNETIC RESONANCE; HIGHER CARBON SUGARS; CLOSING METATHESIS; CARBOHYDRATE-DERIVATIVES; ENANTIOMERICALLY PURE; D-GLUCOSE; STEREOCONTROLLED FUNCTIONALIZATION; CLAISEN REARRANGEMENT;

D O I：

10.2174/1385272819666140527224344

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methodologies for the synthesis of polyhydroxylated carbocyclic derivatives with medium (7- and 8-member) rings are reviewed. Polyhydroxylated carbocyclic derivatives with larger rings are practically unknown; only few examples can be found in the literature. This review is focused on the methods of preparation rather than on the size of cyclitols. Various types of compounds with medium carbocyclic rings are discussed. Selected examples of polyhydroxylated derivatives with very large rings, containing also heteroatoms in the cyclic framework, are also reported.

引用

页码：1674 / 1685

页数：12

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