Dimorphism SmA-B2 in bent-core mesogens with perfluorinated terminal chains

被引:43
作者
Kovalenko, L
Weissflog, W
Grande, S
Diele, S
Pelzl, G
Wirth, I
机构
[1] Univ Halle Wittenberg, Inst Phys Chem, D-06108 Halle, Germany
[2] Univ Leipzig, Fak Phys & Geowissensch, D-04103 Leipzig, Germany
关键词
D O I
10.1080/026782900202552
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Several banana-shaped liquid crystal materials with perfluorinated terminal chains have been synthesized. A dimorphism SmA-B-2 was proved by X-ray studies and electro-optical measurements. The unusual ratio d/L (d = layer spacing, L = molecular length) and the unexpected behaviour of the layer spacing at the phase transition SmA --> B-2 can be interpreted by a change of the packing of the bent molecules.
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收藏
页码:683 / 687
页数:5
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