Metal-free mechanochemical oxidations in Ertalyte® jars

被引：20
作者：
Porcheddu, Andrea [1 ]
Delogu, Francesco [2 ]
De Luca, Lidia [3 ]
Fattuoni, Claudia [1 ]
Colacino, Evelina [4 ,5 ]
机构：
[1] Univ Cagliari, Dipartimento Sci Chim & Geol, SS 554 Bivio Sestu, I-09042 Monserrato, Ca, Italy
[2] Univ Cagliari, Dipartimento Ingn Meccan Chim & Mat, Via Marengo 2, I-09123 Cagliari, Italy
[3] Univ Sassari, Dipartimento Chim & Farm, Via Vienna 2, I-07100 Sassari, Italy
[4] Univ Montpellier, 8 Rue Ecole Normale, F-34296 Montpellier 5, France
[5] ICGM, UMR CNRS UM ENSCM 5253, 8 Rue Ecole Normale, F-34296 Montpellier 5, France
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 15卷
关键词：
AZADO; Ertalyte (R); green chemistry; mechanochemistry; NaOCl center dot 5H(2)O; selective oxidation; TEMPO; PENTAHYDRATE NAOCL-CENTER-DOT-5H(2)O CRYSTALS; ALCOHOL OXIDATION; SELECTIVE OXIDATION; AEROBIC OXIDATION; MEDICINAL MECHANOCHEMISTRY; OXOAMMONIUM SALTS; MODEL COMPOUNDS; ALDEHYDES; TEMPO; KETONES;
D O I：
10.3762/bjoc.15.172
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aimed at eliminating or at least significantly reducing the use of solvents, sodium hypochlorite pentahydrate crystals (NaOCl center dot 5H(2)O) in the presence of a catalytic amount of a nitrosyl radical (TEMPO or AZADO) have been successfully used to induce mechanochemical oxidative processes on several structurally different primary and secondary alcohols. The proposed redox process is safe, inexpensive and performing effectively, especially on the macroscale. Herein, an Ertalyte (R) jar has been successfully used, for the first time, in a mechanochemical process.
引用
收藏
页码：1786 / 1794
页数：9
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