Graphene decorated by Co2(OH)3Cl: A promising lightweight wideband microwave absorber

被引:5
作者
Zhao, Xiaolu [1 ,3 ]
Li, Ji [2 ]
Liu, Jipeng [2 ]
Zhang, Lei [2 ]
Yang, Chunhui [2 ]
机构
[1] Chinese Acad Sci, Tech Inst Phys & Chem, CAS Key Lab Bioinspired Mat & Interfacial Sci, Beijing 100190, Peoples R China
[2] Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Heilongjiang, Peoples R China
[3] Univ Chinese Acad Sci, Sch Future Technol, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
Nanomaterials; Carbon; Co-2(OH)(3)Cl; Electromagnetic wave absorption; ELECTROMAGNETIC PROPERTIES; ABSORPTION PROPERTIES; COMPOSITES; PERFORMANCE; DESIGN; NANOPARTICLES; ELECTRODE; MECHANISM; STRATEGY; PROPERTY;
D O I
10.1016/j.jallcom.2019.151905
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A wideband microwave absorber is requested to have the impedance matching and attenuation ability, which can be realized by the general strategy of component-optimization. Taking graphene-based hybrids for an example, the impedance matching ability can be significant improved when combining graphene with others components with lower dielectric properties. However, the benefited component usually has poor dielectric loss ability undermining the overall attenuation ability. To address this issue, this research reports a progress on the nanostructure of promising component by the in-situ growth of nanoflake-like Co-2(OH)(3)Cl on graphene, which is favorable for boosting the dielectric-response to the microwaves. As a result, the composite showed superior performance with the ultralow density of merely 0.1 0.01 g/cm(3). A minimal reflection loss (R-L) value of -52 dB could be achieved with a loading ratio of 20 wt% with a thickness of merely 1.42 mm. Meanwhile, the qualified frequency region is -3.44 GHz. To investigate the attenuation mechanism, more Co-2(OH)(3)Cl/graphene hybrids were developed by tuning the reaction conditions, e.g., pH values, starting amount of Co slates etc. Synthesizing nanocomposite of Co-2(OH)(3)Cl and graphene opens a new avenue toward the more efficient electromagnetic absorption devices. (C) 2019 Elsevier B.V. All rights reserved.
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页数:9
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