Production of oil palm (Elaeis guineensis) fronds lignin-derived non-toxic aldehyde for eco-friendly wood adhesive

被引：59
作者：
Hussin, M. Hazwan [1 ]
Samad, Noraini Abdul [1 ]
Abd Latif, Nur Hanis [1 ]
Rozuli, Nurul Adilla [1 ]
Yusoff, Siti Baidurah [2 ]
Gambier, Francois [3 ]
Brosse, Nicolas [3 ]
机构：
[1] Univ Sains Malaysia, Sch Chem Sci, Mat Technol Res Grp MaTReC, Minden 11800, Penang, Malaysia
[2] Univ Sains Malaysia, Bioproc Technol Div, Sch Ind Technol, Minden 11800, Penang, Malaysia
[3] Univ Lorraine, Fac Sci & Tech, Lab Etud & Rech Mat Bois LERMAB, F-54500 Vandoeuvre Les Nancy, France
来源：
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES | 2018年 / 113卷
关键词：
Oil palm fronds; Organosolv lignin; Glyoxal; Wood adhesive; PHENOL-FORMALDEHYDE RESIN; PHYSICOCHEMICAL CHARACTERIZATION; KRAFT LIGNIN; TANNIN; ORGANOSOLV; BIOMASS; PANELS; LIGNOSULFONATE; MECHANISM; ALKALINE;
D O I：
10.1016/j.ijbiomac.2018.03.048
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Lignocellulosic materials can significantly contribute to the development of eco-friendly wood adhesives. In this work, glyoxal-phenolic resins for plywood were prepared using organosolv lignin, which was isolated from black liquor recovered from organosolv pulping of oil palm fronds (OPF) and considered to be an alternative to phenol. Glyoxal, which is a dialdehyde obtained from several natural resources, was used as substitute for formaldehyde. The structure of organosolv lignin and the resins were characterized by FTIR and NMR, and for thermal stability by TGA and DSC. The resins were further studied for their viscosity, pH, solids content and gel times. The resins performance as wood adhesive was further established from mechanical test in terms of tensile strength and modulus of elasticity (MOE) to obtain the optimum ratios of organosolv lignin, which replaces phenol in organosolv lignin phenol glyoxal (OLPG) resins. The adhesive composition having 50% (w/w) of phenol substituted by organosolv lignin, termed as 50% OLPG showed highest adhesive strength compared to phenol formaldehyde (PF) commercial adhesive. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码：1266 / 1272
页数：7
相关论文
共 42 条
[11]   Lignin-based wood panel adhesives without formaldehyde [J].
El Mansouri, Nour-eddine ;
Pizzi, Antonio ;
Salvado, Joan .
HOLZ ALS ROH-UND WERKSTOFF, 2007, 65 (01) :65-70
[12]   Structural characterization of technical lignins for the production of adhesives:: Application to lignosulfonate, kraft, soda-anthraquinone, organosolv and ethanol process lignins [J].
El Mansouri, Nour-Eddine ;
Salvado, Joan .
INDUSTRIAL CROPS AND PRODUCTS, 2006, 24 (01) :8-16
[13]  
El Mansouri NE, 2011, BIORESOURCES, V6, P4523
[14]  
Fink JohannesKarl., 2005, REACTIVE POLYM FUNDA
[15]   Characterization of lignins obtained by selective precipitation [J].
Garcia, A. ;
Toledano, A. ;
Serrano, L. ;
Eguees, I. ;
Gonzalez, M. ;
Marin, F. ;
Labidi, J. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2009, 68 (02) :193-198
[16]   Polyphenolic resins prepared with maritime pine bark tannin and bulky-aldehydes [J].
Garcia, D. E. ;
Glasser, W. G. ;
Pizzi, A. ;
Lacoste, C. ;
Laborie, M. -P. .
INDUSTRIAL CROPS AND PRODUCTS, 2014, 62 :84-93
[17]  
Geoffrey E. H., 1993, HOLZFROSCHUNG, V47, P302
[18]  
Hussin M.H., 2017, BeniSuef Uni. J. Basic Appl. Sci, V6, P409, DOI [10.1016/j. bjbas.2017.06.004, DOI 10.1016/J.BJBAS.2017.06.004]
[19]   Physicochemical characterization of alkaline and ethanol organosolv lignins from oil palm (Elaeis guineensis) fronds as phenol substitutes for green material applications [J].
Hussin, M. Hazwan ;
Rahim, Afidah Abdul ;
Ibrahim, Mohamad Nasir Mohamad ;
Brosse, Nicolas .
INDUSTRIAL CROPS AND PRODUCTS, 2013, 49 :23-32
[20]  
Ibrahim M., 2007, J. Anal. Sci., V11, P213, DOI [10.1007/s10640-022-00647-4, DOI 10.1007/S10640-022-00647-4]
12345