The first example of a bis-monohelical complex: The crystal and molecular structure of [Mn-2(dmqpy)(2)(H2O)(2)(mu-Cl)][ClO4](3)center dot 4H(2)O (dmqpy=6,6''''-dimethyl-2,2':6',2'':6'',2''':6''''-quinquepyridine)

被引:15
作者
Fu, YJ
Li, Q
Zhou, ZY
Dai, WN
Wang, DF
Mak, TCW
Hu, HW
Tang, WX
机构
[1] NANJING UNIV,INST COORDINAT CHEM,STATE KEY LAB COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA
[2] CHINESE UNIV HONG KONG,DEPT CHEM,SHATIN,NEW TERRITORIES,HONG KONG
关键词
D O I
10.1039/cc9960001549
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
6,6''''-Dimethyl-2,2':6',2 '' 6 '',2'''': 6''',2''''-quinquepyridine (dmqpy) is found to form a dinuclear complex with manganese(II), the structure of which is not double helical but composed of two shallow monohelical complex cations bridged by a chloride ion.
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页码:1549 / 1550
页数:2
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