Self-assembled three-dimensional hierarchical Bi2WO6 microspheres by sol-gel-hydrothermal route

被引:34
作者
Liu, Yumin [1 ]
Tang, Haibo [1 ]
Lv, Hua [1 ]
Li, Zijin [1 ]
Ding, Zhiwei [1 ]
Li, Shuang [1 ]
机构
[1] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
基金
中国国家自然科学基金;
关键词
Porosity; Bi2WO6; Photocatalytic; Sol-gel hydrothennal; PHOTOCATALYTIC DECOMPOSITION; ORGANIC CONTAMINANTS; FABRICATION; TIO2; NANOCRYSTALS; PERFORMANCE;
D O I
10.1016/j.ceramint.2013.11.075
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Self-assembled three-dimensional (3D) hierarchical Bi2WO6 microspheres built from 2D nanoplates alignment were successfully prepared by the sol gel hydrothermal route. Based on X-ray diffraction and scanning electron microscopy observation of the products at different reaction time periods, the formation mechanism of 3D hierarchical Bi2WO6 microspheres was proposed. UV vis diffuse reflectance spectra indicated that the obtained 3D hierarchical Bi2WO6 microspheres had enhanced absorption in both UV and visible light regions. The photocatalytic activities of the as-prepared products were evaluated by monitoring the degradation of methylene blue solution under visible light irradiation. Due to the structural feature and good optical quality, Bi2WO6 prepared by the sol gel hydrothermal route possessed the highest photocatalytic activity than those of Bi2WO6 samples prepared by hydrothermal and sol gel routes. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:6203 / 6209
页数:7
相关论文
共 31 条
[11]   Photocatalytic degradation of Reactive Brilliant Blue KN-R by TiO2/UV process [J].
Liu, Yumin ;
Hua, Lv ;
Li, Shuangqing .
DESALINATION, 2010, 258 (1-3) :48-53
[12]   Self-Assembled Three-Dimensional Hierarchical Umbilicate Bi2WO6 Microspheres from Nanoplates: Controlled Synthesis, Photocatalytic Activities, and Wettability [J].
Ma, Dekun ;
Huang, Shaoming ;
Chen, Wenxiu ;
Hu, Shengwei ;
Shi, Fangfang ;
Fan, Kellei .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (11) :4369-4374
[13]   Solvent directed fabrication of Bi2WO6 nanostructures with different morphologies: Synthesis and their shape-dependent photocatalytic properties [J].
Mi, Yuwei ;
Zeng, Suyuan ;
Li, Lei ;
Zhang, Qingfu ;
Wang, Suna ;
Liu, Caihua ;
Sun, Dezhi .
MATERIALS RESEARCH BULLETIN, 2012, 47 (09) :2623-2630
[14]   Synthesis, characterization and visible-light photocatalytic properties of Bi2WO6 and Bi2W2O9 obtained by co-precipitation method [J].
Obregon Alfaro, S. ;
Martinez-de la Cruz, A. .
APPLIED CATALYSIS A-GENERAL, 2010, 383 (1-2) :128-133
[15]   Bi2WO6 with significantly enhanced photocatalytic activities by nitrogen doping [J].
Shang, Meng ;
Wang, Wenzhong ;
Zhang, Ling ;
Xu, Haolan .
MATERIALS CHEMISTRY AND PHYSICS, 2010, 120 (01) :155-159
[16]   Photocatalytic decomposition of organic contaminants by Bi2WO6 under visible light irradiation [J].
Tang, JW ;
Zou, ZG ;
Ye, JH .
CATALYSIS LETTERS, 2004, 92 (1-2) :53-56
[17]   Efficient photocatalytic decomposition of organic contaminants over CaBi2O4 under visible-light irradiation [J].
Tang, JW ;
Zou, ZG ;
Ye, JH .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (34) :4463-4466
[18]   Surface science studies of the photoactivation of TiO2-new photochemical processes [J].
Thompson, Tracy L. ;
Yates, John T., Jr. .
CHEMICAL REVIEWS, 2006, 106 (10) :4428-4453
[19]   Preparation of TiO2 hollow microspheres by a novel vesicle template method and their enhanced photocatalytic properties [J].
Wang, Ran ;
Cai, Xia ;
Shen, Fenglei .
CERAMICS INTERNATIONAL, 2013, 39 (08) :9465-9470
[20]   Polymer-induced alignment of DL-alanine nanocrystals to crystalline mesostructures [J].
Wohlrab, S ;
Pinna, N ;
Antonietti, M ;
Cölfen, H .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (10) :2903-2913