Heterometallic 3d-4f cubane clusters inserted in polyoxometalate matrices

被引:98
作者
Nohra, Brigitte [1 ]
Mialane, Pierre [1 ]
Dolbecq, Anne [1 ]
Riviere, Eric [2 ]
Marrot, Jerome [1 ]
Secheresse, Francis [1 ]
机构
[1] Univ Versailles, UMR 8180, Inst Lavoisier Versailles, F-78035 Versailles, France
[2] Univ Paris 11, UMR 8182, Inst Chim Mol & Mat Orsay, Equipe Chim Inorgan, F-91405 Orsay, France
关键词
HYDROTHERMAL SYNTHESIS; RARE-EARTH; COMPLEXES; FUNCTIONALIZATION; AGGREGATE; LINKERS;
D O I
10.1039/b902094b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Unprecedented molecular and bidimensional compounds based on monovacant polyoxometalates capped by heterometallic 3d-4f {LnCu(3)(OH)(3)O} (Ln= La, Gd, Eu) cubane fragments have been characterized and their magnetic properties investigated.
引用
收藏
页码:2703 / 2705
页数:3
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