Low-temperature fabrication of brown TiO2 with enhanced photocatalytic activities under visible light

被引:71
作者
Wang, Mingzheng [1 ,2 ,3 ]
Nie, Biao [2 ,3 ]
Yee, Ka-Kit [4 ]
Bian, Haidong [2 ,3 ,4 ]
Lee, Chris [2 ,3 ]
Lee, Hung Kay [5 ]
Zheng, Bo [5 ]
Lu, Jian [6 ,7 ,8 ]
Luo, Linbao [1 ]
Li, Yang Yang [2 ,3 ,9 ]
机构
[1] Hefei Univ Technol, Sch Elect Sci & Appl Phys, Hefei 230009, Anhui, Peoples R China
[2] City Univ Hong Kong, Ctr Funct Photon, Ctr Super Diamond & Adv Films COSDAF, Kowloon, Hong Kong, Peoples R China
[3] City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon, Hong Kong, Peoples R China
[4] City Univ Hong Kong, Dept Biol & Chem, Kowloon, Hong Kong, Peoples R China
[5] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
[6] City Univ Hong Kong, Dept Mech & Biomed Engn, Kowloon, Hong Kong, Peoples R China
[7] City Univ Hong Kong, Ctr Adv Struct Mat, Kowloon, Hong Kong, Peoples R China
[8] City Univ Hong Kong, Shenzhen Res Inst, Ctr Adv Struct Mat, 8 Yuexing 1st Rd,Shenzhen Hitech Ind Pk, Shenzhen, Peoples R China
[9] City Univ Hong Kong, Shenzhen Res Inst, 8 Yuexing 1st Rd,Shenzhen Hitech Ind Pk, Shenzhen, Peoples R China
关键词
DOPED TIO2; NANOTUBE ARRAYS; HYDROGENATED TIO2; WATER; ABSORPTION; NANOPARTICLES; BANDGAP; METAL;
D O I
10.1039/c5cc09176d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Here we report a facile one-step low-temperature solution-based method to treat native TiO2 with NaH. The NaH treatment effectively induces the Ti(III) species and oxygen vacancies into the TiO2 host lattice, and enables the absorption edge of TiO2 to be conveniently adjusted from the UV region to the red end of the visible spectrum.
引用
收藏
页码:2988 / 2991
页数:4
相关论文
共 40 条
[1]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[2]   Enhanced nitrogen doping in TiO2 nanoparticles [J].
Burda, C ;
Lou, YB ;
Chen, XB ;
Samia, ACS ;
Stout, J ;
Gole, JL .
NANO LETTERS, 2003, 3 (08) :1049-1051
[3]   Photoinduced reactivity of titanium dioxide [J].
Carp, O ;
Huisman, CL ;
Reller, A .
PROGRESS IN SOLID STATE CHEMISTRY, 2004, 32 (1-2) :33-177
[4]   The electronic origin of the visible-light absorption properties of C-, N- and S-doped TiO2 nanomaterials [J].
Chen, Xiaobo ;
Burda, Clemens .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (15) :5018-+
[5]   Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications [J].
Chen, Xiaobo ;
Mao, Samuel S. .
CHEMICAL REVIEWS, 2007, 107 (07) :2891-2959
[6]   Properties of Disorder-Engineered Black Titanium Dioxide Nanoparticles through Hydrogenation [J].
Chen, Xiaobo ;
Liu, Lei ;
Liu, Zhi ;
Marcus, Matthew A. ;
Wang, Wei-Cheng ;
Oyler, Nathan A. ;
Grass, Michael E. ;
Mao, Baohua ;
Glans, Per-Anders ;
Yu, Peter Y. ;
Guo, Jinghua ;
Mao, Samuel S. .
SCIENTIFIC REPORTS, 2013, 3
[7]   Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals [J].
Chen, Xiaobo ;
Liu, Lei ;
Yu, Peter Y. ;
Mao, Samuel S. .
SCIENCE, 2011, 331 (6018) :746-750
[8]   THE ROLE OF METAL-ION DOPANTS IN QUANTUM-SIZED TIO2 - CORRELATION BETWEEN PHOTOREACTIVITY AND CHARGE-CARRIER RECOMBINATION DYNAMICS [J].
CHOI, WY ;
TERMIN, A ;
HOFFMANN, MR .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (51) :13669-13679
[9]   TiO2 hollow spheres with large amount of exposed (001) facets for fast reversible lithium storage [J].
Ding, Shujiang ;
Chen, Jun Song ;
Wang, Zhiyu ;
Cheah, Yan Ling ;
Madhavi, Srinvivasan ;
Hu, Xiao ;
Lou, Xiong Wen .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (06) :1677-1680
[10]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+