Synthesis and luminescence properties of Li2O-Y2O3-TeO2:Eu3+ tellurite glass

被引：9
作者：
Atuchin, V. V. [1 ,2 ,3 ]
Yelisseyev, A. P. [4 ]
Galashov, E. N. [5 ]
Molokeev, M. S. [6 ]
机构：
[1] SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
[2] Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
[3] Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia
[4] SB RAS, Inst Geol & Mineral, Lab High Pressure Minerals & Diamond Deposits, Novosibirsk 630090, Russia
[5] Novosibirsk State Univ, Dept Appl Phys, Novosibirsk 630090, Russia
[6] SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia
来源：
MATERIALS CHEMISTRY AND PHYSICS | 2014年 / 147卷 / 03期
关键词：
Glasses; Heat treatment; Photoluminescence spectroscopy; Optical properties; SPECTROSCOPIC PROPERTIES; OPTICAL-PROPERTIES; ENERGY-TRANSFER; EU3+; PHOTOLUMINESCENCE; TEMPERATURE; EMISSION; PHOSPHOR; SALT;
D O I：
10.1016/j.matchemphys.2014.07.003
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The Eu3+-doped red-orange emitting phosphor of tellurite glass 0.25Li(2)O-0.20Y(2)O(3)-0.5TeO(2)-0.05Eu(2)O(3) has been synthesized by the melt quenching method. The amorphous nature of the glass has been verified by XRD measurements. The photoluminescence excitation and emission spectra, the luminescence decay curves have been investigated for the composition. The phosphor can be efficiently excited by the near UV light to realize the intense narrow red emission line (611 nm) corresponding to forced electric dipole transition D-5(0) -> E-7(2) of Eu3+ ions. The Li2O-Y2O3-TeO2:Eu(3+)glass phosphor is a potential red-orange emitting candidate for the application in WLEDs. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：1191 / 1194
页数：4
相关论文
共 26 条
[1]   Synthesis and Spectroscopic Properties of Monoclinic α-Eu2(MoO4)3 [J].
Atuchin, V. V. ;
Aleksandrovsky, A. S. ;
Chimitova, O. D. ;
Gavrilova, T. A. ;
Krylov, A. S. ;
Molokeev, M. S. ;
Oreshonkov, A. S. ;
Bazarov, B. G. ;
Bazarova, J. G. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (28) :15404-15411
[2]   Low-temperature synthesis and structural properties of ferroelectric K3WO3F3 elpasolite [J].
Atuchin, V. V. ;
Gavrilova, T. A. ;
Kesler, V. G. ;
Molokeev, M. S. ;
Aleksandrov, K. S. .
CHEMICAL PHYSICS LETTERS, 2010, 493 (1-3) :83-86
[3]   Effects of Er3+ :Ag codoping on structural and spectroscopic properties of lead tellurite glass ceramics [J].
Culea, Eugen ;
Vida-Simiti, Ioan ;
Borodi, Gheorghe ;
Culea, Eugen Nicolae ;
Stefan, Razvan ;
Pascuta, Petru .
CERAMICS INTERNATIONAL, 2014, 40 (07) :11001-11007
[4]   Electronic polarizability, optical basicity and non-linear optical properties of oxide glasses [J].
Dimitrov, V ;
Komatsu, T .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1999, 249 (2-3) :160-179
[5]   Enhanced photoluminescence from mixed-valence Eu-doped nanocrystalline silicate glass ceramics [J].
Gao, Guojun ;
Da, Ning ;
Reibstein, Sindy ;
Wondraczek, Lothar .
OPTICS EXPRESS, 2010, 18 (23) :A575-A583
[6]   Spectroscopic Investigations of Eu3+ and Tb3+: Cadmium Lead Boro Tellurite Glasses [J].
Giridhar, P. ;
Seo, Hyo Jin ;
Sailaja, S. ;
Reddy, M. Bhushana ;
Raju, C. Nageswara ;
Reddy, B. Sudhakar .
GLASS PHYSICS AND CHEMISTRY, 2012, 38 (01) :77-84
[7]   Spectroscopic Studies of RE3+ (RE=Eu, Tb, Sm & Dy): Lithium Lead Boro Tellurite Glasses [J].
Giridhar, P. ;
Sailaja, S. ;
Reddy, M. Bhushana ;
Raju, K. Vemasevana ;
Raju, C. Nageswara ;
Reddy, B. Sudhakar .
FERROELECTRICS LETTERS SECTION, 2011, 38 (1-3) :1-10
[8]   SPECTROSCOPIC ANALYSIS OF THE STRUCTURE AND PROPERTIES OF ALKALI TELLURITE GLASSES [J].
HEO, J ;
LAM, D ;
SIGEL, GH ;
MENDOZA, EA ;
HENSLEY, DA .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1992, 75 (02) :277-281
[9]   Rare earth doping into optical nonlinear nanocrystalline phase in transparent TeO2-based glass-ceramics [J].
Hirano, K ;
Benino, Y ;
Komatsu, T .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2001, 62 (11) :2075-2082
[10]   THEORY OF URBACH RULE [J].
KEIL, TH .
PHYSICAL REVIEW, 1966, 144 (02) :582-&
123