N,N-dimethylcarbamato complexes of zinc

被引：13

作者：

Dell'Amico, Daniela Belli ^{[1
]}

Calderazzo, Fausto ^{[1
]}

Labella, Luca ^{[1
]}

Marchetti, Fabio ^{[1
]}

Mazzoncini, Ilaria ^{[1
]}

机构：

[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 10期

关键词：

zinc complexes; carbamato complexes; carbon dioxide; hydrolysis;

D O I：

10.1016/j.ica.2006.03.025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By reaction of Zn4O(O2CNMe2)(6) (1) with [NH2Me2][O2CNMe2] in toluene as medium, the homoleptic zinc compound [Zn(O2CNMe2)(2)] (2) was obtained, which reverted back to the tetranuclear mu-oxo derivative by controlled hydrolysis. The reaction of ZnO in MeCN with an excess of [NH2Me2][O2CNMe2] in concentrated solution produced high yields of [Zn(O2CNMe2)(2)] (2) or [NH2Me2][Zn-2(O2CNMe2)(5)] center dot xMeCN, 3 center dot xMeCN, x = 1 or 2, depending on the experimental conditions. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：3371 / 3374

页数：4

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