Hydrothermal synthesis, structure and properties of a new 3D two-fold Co-based coordination framework

被引：1

作者：

Chen, Man-Sheng ^{[1
,2
]}

Li, Xiao-Jie ^{[1
,2
]}

Deng, Yi-Fang ^{[1
,2
]}

Zhang, Chun-Hua ^{[1
,2
]}

Sheng, Liang-Bing ^{[1
,2
]}

Lu, Wei-Hong ^{[1
,2
]}

机构：

[1] Hengyang Normal Univ, Coll Hunan Prov, Coll Chem & Mat Sci, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang, Peoples R China

[2] Hengyang Normal Univ, Coll Hunan Prov, Coll Chem & Mat Sci, Key Lab Funct Organometall Mat Hengyang Normal U, Hengyang, Peoples R China

来源：

INORGANIC AND NANO-METAL CHEMISTRY | 2021年 / 51卷 / 11期

关键词：

Coordination polymer; hydrothermal reaction; electrochemical; degradation; DEGRADATION; POLYMERS; LIGANDS;

D O I：

10.1080/24701556.2020.1852255

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D coordination polymer, [Co-2(MIP)(2)(BMIP)] (n) (1), [H2MIP = 5-methyl-isophthalic acid, BMIP = 1,5-bis-(2-methyl-imidazol)pentane] has been synthesized and characterized by single crystal X-ray diffraction analysis. The results of structural analyses show that 1 has a two-fold interpenetrated 3D network with a pcu topology. In addition, the luminescent, electrochemical properties and degradation of MB and MO of the complex were studied. The photocatalytic mechanism was proposed and confirmed by trapping experiments of radical species.

引用

页码：1591 / 1597

页数：7

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