Dielectric, piezoelectric properties of MnO2-doped (K0.5Na0.5) NbO3-0.05LiNbO3 crystal grown by flux-Bridgman method

Lead-free potassium sodium niobate piezoelectric single crystals substituted with lithium and then doped with MnO2 (K0.5Na0.5)NbO3-0.05LiNbO(3)-yMnO(2) (y = 0%, 1.0% and 1.5%) (abbreviated as KNN-0.05LN-yMnO(2)) have been grown by flux-Bridgman method using KCl-K2CO3 eutectic composition as the flux. Their actual composition as well as the dielectric and piezoelectric properties were studied. Their actual composition deviated from the ratio of the raw materials due to different segregation coefficients of K and Na. The orthorhombic-tetragonal (To-t) and tetragonal-cubic phase transition temperature (the Curie temperature T-c) of the single crystal appears at 186 degrees C and 441 degrees C, respectively, for KNN-0.05LN-1.0% MnO2, shift to higher temperatures compared with that of pure KNN-0.05LN crystals, according to the dielectric permittivity versus temperature loops. The KNN-0.05LN-1.0% MnO2 (001) plate shows higher piezoelectric coefficient d(33) and dielectric permittivity er when compared with pure KNN-0.05LN crystal, being on the order of 226 pC/N and 799 (161 pC/N and 530 for KNN-0.05LN), respectively. These excellent properties show that MnO2 dopant is effective in improving KNN-0.05LN based piezoelectric crystals. (C) 2014 Elsevier B. V. All rights reserved.