An engineered N-H•••π interaction:: crystal structure of 4-tritylbenzamide-p-xylene (2:1)

被引:18
作者
Reddy, CM
Nangia, A [1 ]
Lam, CK
Mak, TCW
机构
[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India
[2] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
关键词
D O I
10.1039/b202297d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title host-guest crystal structure is designed to contain an N-H⋯π interaction. The crystal structure is stabilised by an N-H⋯O hydrogen-bonded amide dimer and weak N-H⋯π and C-H⋯O hydrogen bonds. The phenyl rings of triphenylmethyl groups interact via the edge-to-face herringbone T-motif. © 2002 The Royal Society of Chemistry.
引用
收藏
页码:323 / 325
页数:3
相关论文
共 22 条
[21]   Hydrogen bonds with π-acceptors in proteins:: Frequencies and role in stabilizing local 3D structures [J].
Steiner, T ;
Koellner, G .
JOURNAL OF MOLECULAR BIOLOGY, 2001, 305 (03) :535-557
[22]  
Weber E, 2002, EUR J ORG CHEM, V2002, P856