Novel crown ether and salen metal chelation driven molecular pincers

被引：22

作者：

Abe, Aki M. M. ^{[1
]}

Helaja, Juho ^{[1
]}

Koskinen, Ari M. P. ^{[1
]}

机构：

[1] Helsinki Univ Technol, Organ Chem Lab, TKK, FI-02015 Helsinki, Finland

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 20期

关键词：

MACROCYCLIC POLYETHERS; COMPLEXES; ION; RECOGNITION; CATALYSIS; RECEPTORS; TWEEZERS; SENSORS; BINDING; CATIONS;

D O I：

10.1021/ol061726o

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of novel metal chelation driven molecular pincers based on crown ether and salen ligand substructures are described. Their functionality was monitored by fluorescence spectroscopy using pyrene groups as fluorescence probes. The pincer was shown to function reversibly with respect to metal chelation with Zn2+ and also to chelate ditopically with 100 mol % of Zn2+ and 100 mol % Li+ or 200 mol % of Li+ ion.

引用

页码：4537 / 4540

页数：4

共 23 条

[1]

Balzani V, 2000, ANGEW CHEM INT EDIT, V39, P3348, DOI 10.1002/1521-3773(20001002)39:19<3348::AID-ANIE3348>3.0.CO

[2]

2-X

[3]

BALZCMI V, 2003, MOL DEVICES MACHINES

[4]

Bogaschenko T, 2002, SYNTHESIS-STUTTGART, P2266

[5] Signaling recognition events with fluorescent sensors and switches [J].

de Silva, AP ;

Gunaratne, HQN ;

Gunnlaugsson, T ;

Huxley, AJM ;

McCoy, CP ;

Rademacher, JT ;

Rice, TE .

CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566

[6] SPECIFIC DNA CLEAVAGE MEDIATED BY [SALENMN(III)]+ [J].

GRAVERT, DJ ;

GRIFFIN, JH .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (04) :820-822

[7]

Gromov S.P., 1999, J CHEM SOC P2, V7, P1323

[8] ARTIFICIAL ALLOSTERIC RECEPTORS FOR NUCLEOTIDE BASES AND ALKALI-METAL CATIONS [J].

INOUYE, M ;

KONISHI, T ;

ISAGAWA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (18) :8091-8095

[9] HIGHLY ENANTIOSELECTIVE EPOXIDATION CATALYSTS DERIVED FROM 1,2-DIAMINOCYCLOHEXANE [J].

JACOBSEN, EN ;

ZHANG, W ;

MUCI, AR ;

ECKER, JR ;

DENG, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (18) :7063-7064

[10] Molecular tweezers and clips as synthetic receptors.: Molecular recognition and dynamics in receptor-substrate complexes [J].

Klärner, FG ;

Kahlert, B .

ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (12) :919-932

← 1 2 3 →