Palladium-catalyzed ortho-acylation of 2-benzyl-1,2,3-triazoles with aldehydes

被引：19
作者：
Tian, Qingshan [1 ]
He, Ping [1 ]
Kuang, Chunxiang [1 ,2 ]
机构：
[1] Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China
[2] Minist Educ, Key Lab Yangtze River Water Environm, Shanghai 200092, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2014年 / 12卷 / 38期
关键词：
C-H BONDS; DECARBOXYLATIVE ORTHO-ACYLATION; ALPHA-OXOCARBOXYLIC ACIDS; TOLUENE DERIVATIVES; DIRECT ARYLATIONS; BENZOIC-ACIDS; RUTHENIUM; FUNCTIONALIZATION; ACETANILIDES; ACTIVATION;
D O I：
10.1039/c4ob01406e
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A palladium-catalyzed ortho-acylation of 2-benzyl-1,2,3-triazoles with aldehydes as an acyl source was developed. A wide variety of ketones containing 1,2,3-triazoles were obtained in good to excellent yields. This methodology provides a convenient access to the acylation of 2-substituted-1,2,3-triazoles.
引用
收藏
页码：7474 / 7477
页数：4
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