Copper(II) Complex Based on 3-Methyl-4-(4-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole

被引：0

作者：

Wang Zuo-Xiang ^{[1
]}

Gong Xiao-Ning ^{[1
]}

Qu Zhi-Rong ^{[1
]}

Wu Ping-Feng ^{[1
]}

Zhang Xiao-Ming ^{[1
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 210096, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 25卷 / 03期

关键词：

copper(II) complex; crystal structure; fluorescence; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; DESIGN; 1,2,4-TRIAZOLE; TRINUCLEAR; CHEMISTRY; DERIVATIVES; TRIAZOLE; CORE;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A copper(II) complex [CuL(H2O)(Sal)]center dot 0.5H(2)O was obtained by the reaction of copper(II) salicylate with 3-methyl-4-(4-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole (L) in ethanol-water solution at room temperature. The crystal belongs to triclinic system with space group P (1) over bar, and a=0.913 6(4) nm, b=1.122 2(5) nm, c=1.263 3 (7) nm, alpha=67.10(2)degrees, beta=76.37(3)degrees, gamma=68.17(2)degrees, V=1.101(1) nm(3), Z=2. The final refinement gave R-1=0.039 8 and omega R-2=0.106 0 for 3 453 reflections with I>2 sigma(I). This complex is a good purple fluorescent material in solid state at room temperature. CCDC: 685713.

引用

页码：567 / 570

页数：4

共 29 条

[1]

[Anonymous], 1997, SHELXS 97 PROGRAMM L

[2]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[3]

2-Z

[4] Cobalt(II) complexes of pyridazine or triazole containing ligands: spin-state control [J].

Beckmann, U ;

Brooker, S .

COORDINATION CHEMISTRY REVIEWS, 2003, 245 (1-2) :17-29

[5] Polycatenation, polythreading and polyknotting in coordination network chemistry [J].

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :247-289

[6] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

[7] Crystal engineering of NLO materials based on metal-organic coordination networks [J].

Evans, OR ;

Lin, WB .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522

[8] Cyclic trinuclear and chain of cyclic trinuclear copper(II) complexes containing a pyramidal Cu3O(H) core.: Crystal structures and magnetic properties of [Cu3(μ3-OH)(aaat)3(H2O)3](NO3)2•H2O [aaat=3-acetylamino-5-amino-1,2,4-triazolate] and {[Cu3(μ3-OH)(aat)3(μ3-SO4)]•6H2O}n [aat=3-acetylamino-1,2,4-triazolate]:: New cases of spin-frustrated systems [J].

Ferrer, S ;

Lloret, F ;

Bertomeu, I ;

Alzuet, G ;

Borrás, J ;

García-Granda, S ;

Liu-González, M ;

Haasnoot, JG .

INORGANIC CHEMISTRY, 2002, 41 (22) :5821-5830

[9] Trinuclear N,N-bridged copper(II) complexes involving a Cu3OH core:: [Cu3(μ3-OH)L3A(H2O)2]A•(H2O)x {L=3-acetylamino-1,2,4-triazolate;: a = CF3SO3, NO3, ClO4; x = 0, 2} synthesis, X-ray structures, spectroscopy, and magnetic properties [J].

Ferrer, S ;

Haasnoot, JG ;

Reedijk, J ;

Müller, E ;

Cingi, MB ;

Lanfranchi, M ;

Lanfredi, AMM ;

Ribas, J .

INORGANIC CHEMISTRY, 2000, 39 (09) :1859-1867

[10] Mononuclear, oligonuclear and polynuclear metal coordination compounds with 1,2,4-triazole derivatives as ligands [J].

Haasnoot, JG .

COORDINATION CHEMISTRY REVIEWS, 2000, 200 :131-185

← 1 2 3 →