Timing and duration of hydrothermal activity at the Los Bronces porphyry cluster: an update

New geochronological data from the Los Bronces cluster of the Rio Blanco-Los Bronces mega-porphyry Cu-Mo district establish a wide range of magmatism, hydrothermal alteration, and mineralization ages, both in terms of areal extent and time. The northern El Plomo and southernmost Los Piches exploration areas contain the oldest barren porphyritic intrusions with U-Pb ages of 10.8 +/- 0.1 Ma and 13.4 +/- 0.1 Ma, respectively. A hypabyssal barren intrusion adjacent northwesterly to the main pit area yields a slightly younger age of 10.2 +/- 0.3 Ma (San Manuel sector, U-Pb), whereas in the Los Bronces (LB) open-pit area, the present day mineral extraction zone, porphyries range from 8.49 to 6.02 Ma (U-Pb). Hydrothermal biotite and sericite ages are up to 0.5 Ma younger but consistent with the cooling of the corresponding intrusion events of each area. Two quartz-molybdenite B-type veins from the LB open pit have Re-Os molybdenite ages of 5.65 +/- 0.03 Ma and 5.35 +/- 0.03 Ma consistent with published data for the contiguous Rio Blanco cluster. The San Manuel exploration area within the Los Bronces cluster, located about 1.5-2 km southeast of the open-pit extraction zone, shows both the oldest hydrothermal biotite (7.70 +/- 0.07 Ma; 40Ar/39Ar) and breccia cement molybdenite ages (8.36 +/- 0.06 Ma; Re-Os) registered in the entire Rio Blanco-Los Bronces district. These are also older than those reported from the El Teniente porphyry Cu(-Mo) deposit, suggesting that mineralization in the late Miocene to early Pliocene porphyry belt of Central Chile commenced 2 Ma before the previously accepted age of 6.3 Ma.