Asymmetric Oxidation Catalysis by a Porphyrin-Inspired Manganese Complex: Highly Enantioselective Sulfoxidation with a Wide Substrate Scope

被引：60

作者：

Dai, Wen ^{[1
,2
,3
]}

Li, Jun ^{[1
,2
]}

Chen, Bo ^{[1
,2
,3
]}

Li, Guosong ^{[1
,2
]}

Lv, Ying ^{[1
,2
]}

Wang, Lianyue ^{[1
,2
]}

Gao, Shuang ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

[2] Dalian Natl Lab Clean Energy, Dalian, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 22期

关键词：

HYDROGEN-PEROXIDE; (SALEN)MANGANESE(III) COMPLEX; ARYL SULFIDES; EPOXIDATION; CHIRALITY; H2O2; THIOETHERS; LIGANDS; ALKENES;

D O I：

10.1021/ol402612x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first genuinely promising porphyrin-inspired manganese-catalyzed asymmetric sulfoxidation method using hydrogen peroxide has been successfully developed, allowing for rapidly oxidizing (0.5-1.0 h) a wide variety of sulfides in high yields with excellent enantioselectivities (up to >99% ee).

引用

页码：5658 / 5661

页数：4

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