Synthesis of 2-boryl-1,3-butadienes from tributylphosphine stabilized zirconacyclopropenes and alkynes

被引：14

作者：

Botvinik, Alina ^{[1
]}

Quntar, Abed Al Aziz ^{[1
,3
]}

Rubinstein, Avri ^{[2
]}

Srebnik, Morris ^{[1
]}

机构：

[1] Hebrew Univ Jerusalem, Dept Med Chem & Nat Prod, IL-91120 Jerusalem, Israel

[2] Hebrew Univ Jerusalem, Dept Pharmaceut, IL-91120 Jerusalem, Israel

[3] Al Quds Univ, Dept Mat Engn, Fac Engn, Abu Dies, E Jerusalem, Israel

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 20期

关键词：

Boryl zirconacyclopropene; Phosphine; Alkyne insertion; Boryl-1,3-butadiene; DIELS-ALDER; CYCLOADDITION; COMPLEXES; BORON;

D O I：

10.1016/j.jorganchem.2009.05.036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Boryl zirconacyclopropenes stabilized with tributylphosphine react with alkynes (terminal and internal) to give predominately 2-boryl-1,3-butadienes, 5, in 40-81% isolated yields. Products 5 are accompanied by 1-boryl-1,3-butadienes in 8-30% when terminal alkynes are inserted. However, the use of an internal alkyne (3-hexyne) gave predominantly 6c. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：3349 / 3352

页数：4

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