Facile electrosynthesis of π-extended porphyrins

被引：28

作者：

Fang, Yuanyuan ^{[1
]}

Koszelewski, Dominik ^{[2
]}

Kadish, Karl M. ^{[1
]}

Gryko, Daniel T. ^{[2
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

[2] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 64期

关键词：

2-PHOTON ABSORPTION; PATHWAY; ARRAYS;

D O I：

10.1039/c4cc02759k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The facile electrosynthesis of it-extended porphyrins is demonstrated for a series of Zn(II), In(III), Ir(III) and free-base meso-substituted derivatives containing the 4,7-dimethoxynaphthalen-1-yl substituent. Electrochemical data suggest that the overall process initially involves two stepwise one-electron oxidations, followed by an intramolecular oxidative aromatic coupling to give the electrooxidized pi-extended porphyrin.

引用

收藏

页码：8864 / 8867

页数：4

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