Self-assembly of Oligo(phenylisoxazolyl)benzenes Induced by Multiple Dipole-Dipole Interactions

被引:14
|
作者
Haino, Takeharu [1 ]
Ueda, Yuko [1 ]
Hirao, Takehiro [1 ]
Ikeda, Toshiaki [1 ]
Tanaka, Masahiro [1 ]
机构
[1] Hiroshima Univ, Dept Chem, Grad Sch Sci, Higashihiroshima, Hiroshima 7398526, Japan
关键词
DYE ASSEMBLIES; MOLECULAR-RECOGNITION; CIRCULAR-DICHROISM; STACKING; NANOFIBERS; NANORINGS; TOROIDS; TUBULES; SYSTEM; GROWTH;
D O I
10.1246/cl.131023
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have demonstrated that oligo(phenylisoxazolyl)benzenes 3-6 formed polymeric assemblies. The intermolecular associations were discussed using thermodynamic parameters. The formation of the polymeric assemblies were confirmed by DOSY and AFM measurements. The large polymeric structures were observed both in solution and in the solid state. The multiple dipole-dipole interactions were crucial for the supramolecular polymerization of the oligo(phenylisoxazolyl)benzenes.
引用
收藏
页码:414 / 416
页数:3
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