Selective and quantitative synthesis of a linear [3]catenane by two component coordination-driven self-assembly

被引：20

作者：

Singh, Jatinder ^{[1
]}

Kim, Dong Hwan ^{[1
]}

Kim, Eun-Hee ^{[2
]}

Singh, Nem ^{[1
]}

Kim, Hyunuk ^{[3
]}

Hadiputra, Rizky ^{[1
]}

Jung, Jaehoon ^{[1
]}

Chi, Ki-Whan ^{[1
]}

机构：

[1] Univ Ulsan, Dept Chem, Ulsan 44610, South Korea

[2] Korea Basic Sci Inst, Prot Struct Grp, Ochang 28119, Chungbuk, South Korea

[3] Korea Inst Energy Res, Energy Mat Lab, Daejeon 34129, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 48期

关键词：

MOLECULAR MACHINES; CHEMICAL TOPOLOGY; CATENANES; CATENATION; ENCAPSULATION; CATALYSIS; SOLVENT; CAGE;

D O I：

10.1039/c9cc03336j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we report the synthesis of a linear [3] catenane comprised of three interlocking rings, by coordination-driven self-assembly. Naphthalene-based acceptor A1 and triazole-based donor L1 were utilized for the self-assembly reaction, which facilitated the formation of linear [3] catenane topology through synergistic non-covalent intercycler interactions (pi-pi, CH-pi and CH-N).

引用

页码：6866 / 6869

页数：4

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