Coordination architectures of 5-(2-pyridyl)tetrazole-2-acetic acid(Hpytza) ligand with cobalt(II), magnesium(II) and calcium(II)

被引：27

作者：

Wang, Bai Jun ^{[1
]}

Zou, Jian Hua ^{[1
]}

Li, Wu Xiang ^{[1
]}

Wang, Zhong ^{[1
]}

Xu, Bo ^{[1
]}

Li, Shan ^{[1
]}

Zhai, Yong Shai ^{[1
]}

Zhu, Da Liang ^{[1
]}

Li, Qiao Yun ^{[1
]}

Yang, Gao Wen ^{[1
]}

机构：

[1] Changshu Inst Technol, Dept Chem & Mat Engn, Jiangsu Lab Adv Funct Mat, Changshu 215500, Jiangsu, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2014年 / 749卷

关键词：

Coordination compound; Hpytza; Crystal structure; Luminescence; Thermal stabilities; METAL-ORGANIC FRAMEWORK; TETRAZOLE-1-ACETIC ACID; CRYSTAL-STRUCTURES; COMPLEXES; POLYMERS; MN;

D O I：

10.1016/j.jorganchem.2013.10.039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of Hpytza (Hpytza = 5-(2-pyridyl)tetrazole-2-acetic acid) with M(NO3)(2) (M = Co(II), Mg(II), Ca(II)) with the presence of KOH under hydrothermal conditions, produced three novel coordination compounds, [M(pytza)(2)(H2O)(2)] (M = Co(1), Mg(2), Ca(3)). These compounds were structurally characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Compound 1 shows mononuclear structure while 2 and 3 reveal 1D structures via bridging pytza as linker. Furthermore, the luminescence properties of 1-3 at room temperature in the solid state were investigated and the thermal stabilities of 1-3 were discussed, as well. (C) 2013 Elsevier B. V. All rights reserved.

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页码：428 / 432

页数：5

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