Synthesis of ozone from air via a polymer-electrolyte-membrane cell with a doped tin oxide anode

被引：29

作者：

Wang, Yun-Hai ^{[1
]}

Cheng, Shaoan ^{[1
]}

Chan, Kwong-Yu ^{[1
]}

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

GREEN CHEMISTRY | 2006年 / 8卷 / 06期

关键词：

D O I：

10.1039/b516927e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The generation of ozone from air using an electrochemical cell consisting of an air cathode, a polymer-electrolyte-membrane (PEM), and a doped tin oxide anode is reported. This synthesis is environmentally friendly compared to the conventional high-voltage corona discharge process since NOx formation is eliminated; a higher ozone concentration is generated; and lower energy may be required.

引用

页码：568 / 572

页数：5

共 28 条

[1] Ozone dissolution in aqueous systems treatment of the experimental data [J].

Bin, AK .

EXPERIMENTAL THERMAL AND FLUID SCIENCE, 2004, 28 (05) :395-405

[2] Electrolytic generation of ozone on an antimony-doped tin dioxide coated electrode [J].

Cheng, SA ;

Chan, KY .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (03) :D4-D6

[3]

CHEREMISINOFF NP, 2002, HDB WATER WASTEWATER, P449

[4]

Chernik AA, 1997, RUSS J ELECTROCHEM+, V33, P259

[5] A VERSATILE LOW-PRESSURE OZONE SOURCE [J].

COLEMAN, E ;

SIEGRIST, T ;

MIXON, DA ;

TREVOR, PL ;

TREVOR, DJ .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1991, 9 (04) :2408-2409

[6] Electrochemistry and green chemical processes: Electrochemical ozone production [J].

da Silva, LM ;

Santana, MHP ;

Boodts, JFC .

QUIMICA NOVA, 2003, 26 (06) :880-888

[7] ELECTROCATALYSIS OF ANODIC OXYGEN-TRANSFER REACTIONS - EVOLUTION OF OZONE [J].

FENG, JR ;

JOHNSON, DC ;

LOWERY, SN ;

CAREY, JJ .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (10) :2708-2711

[8] Electro-catalytic oxidation of phenol on several metal-oxide electrodes in aqueous solution [J].

Feng, YJ ;

Li, XY .

WATER RESEARCH, 2003, 37 (10) :2399-2407

[9]

FERNANDO JB, 2004, OZONE REACTION KINET, P78

[10] THE ANODIC EVOLUTION OF OZONE [J].

FOLLER, PC ;

TOBIAS, CW .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1982, 129 (03) :506-515

← 1 2 3 →