The influence of ligands on the bonding mode of thiocyanate group in copper(II) complexes with polyamines

被引：0
|
作者：
Macaskova, L
Maslejova, A
Kabesova, M
Melnik, M
机构：
来源：
POLISH JOURNAL OF CHEMISTRY | 1996年 / 70卷 / 03期
关键词：
complexes; synthesis; optical spectra; magnetic susceptibility;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new series of compounds of general formula CuL(2)(NCS)X (where L = N,N'-dimethylethylenediamine (sym-Me(2)en), 1,3-diaminopropane (DAP) and N-aminopropylcyclohexylamine (ACHA) and X = CIO4-, NO3-, BF4-, SCN- has been prepared. Structural properties were characterized by spectral and magnetic measurements. The substitution of one NCS group in Cu(sym-Me(2)en)(2)(NCS)(2) and of one SCN group in Cu(DAP)(2)(SCN)(2) and Cu(ACHA)(2)(SCN)(2) for NO3-, ClO4- and BF4- anions leads to N-coordination of NCS group in these compounds.
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页码：284 / 287
页数：4
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