Thermo-oxidative stability of electron beam irradiated ethylene norbornene copolymer

被引:5
作者
Aymes-Chodur, Caroline [1 ]
Sghaier, M. [1 ]
Yagoubi, N. [1 ]
机构
[1] Univ Paris 11, Fac Pharm 5, Lab Mat & Sante, EA 401,IFR 141, F-92296 Chatenay Malabry, France
关键词
Ethylene norbornene copolymer; TGA; DSC; OIT; Thermo-oxidation; Irganox 1010 (R); OXIDATION INDUCTION TIME; CYCLIC OLEFIN COPOLYMERS; RADIO-STERILIZATION; POLYETHYLENE; ANTIOXIDANT; TEMPERATURE; LEACHABLES;
D O I
10.1016/j.radphyschem.2015.05.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effect of ionizing radiation on the thermal stability of ethylene norbornene copolymer (ENC) to which a phenolic antioxidant (AO), Irganox 1010 (R), had been added, was investigated. To this end, a series of appropriate thermal analyzes methods (TGA, DSC, OIT measurements), were used for testing the polymer matrix oxidation level. We were able to correlate the diminution of AO concentration with the oxidation induction time and calculate the activation energy, thereby demonstrating the efficiency of the AO and the effect of radiation. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:128 / 132
页数:5
相关论文
共 20 条
[1]  
[Anonymous], 1994, AFNORNFEN552
[2]  
[Anonymous], 2013, AFNORNFENISO113576 5
[3]   Effect of electron beam radio sterilization on cyclic olefin copolymers used as pharmaceutical storage materials [J].
Barakat, Hala ;
Aymes-Chodur, Caroline ;
Saunier, Johanna ;
Yagoubi, Najet .
RADIATION PHYSICS AND CHEMISTRY, 2013, 84 :223-231
[4]   Assessment of thermal and thermo-oxidative stability of multiextruded recycled PP, HDPE and a blend thereof [J].
Camacho, W ;
Karlsson, S .
POLYMER DEGRADATION AND STABILITY, 2002, 78 (02) :385-391
[5]   Effect of phenolic phosphite antioxidant on the thermo-oxidative degradation of PMMA [J].
Chang, TC ;
Yu, PY ;
Hong, YS ;
Wu, TR ;
Chiu, YS .
POLYMER DEGRADATION AND STABILITY, 2002, 77 (01) :29-34
[6]  
Commission of the European Communities, 1990, CPMP WORK PART QUAL
[7]   Oxidation induction time and oxidation onset temperature of polyethylene in air [J].
Focke, Walter W. ;
van der Westhuizen, Isbe .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2010, 99 (01) :285-293
[8]   THERMOGRAVIMETRIC STUDIES OF THE THERMOOXIDATIVE STABILITY OF IRRADIATED AND UNIRRADIATED POLYETHYLENE .1. EFFECT OF ANTIOXIDANT [J].
GAL, O ;
NOVAKOVIC, L ;
MARKOVIC, V ;
STANNETT, VT .
RADIATION PHYSICS AND CHEMISTRY, 1983, 22 (3-5) :627-634
[9]   Investigation of antioxidant and electron beam radiation effects on the thermal oxidation stability of low-density polyethylene [J].
Ghaffari, Mehdi ;
Ahmadian, Venus .
RADIATION PHYSICS AND CHEMISTRY, 2007, 76 (11-12) :1666-1670
[10]  
Grenet Jean, 2010, ANAL CALORIMETRIQUE