Microstructural evolution during the ignition/quenching of pre-heated Ti/3Al powders

被引:35
作者
Che, H. Q. [1 ]
Fan, Q. C. [1 ]
机构
[1] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
关键词
TiAl3; intermetallics; Combustion reaction; Microstructural evolution; HIGH-TEMPERATURE SYNTHESIS; TIC-FE CERMET; COMBUSTION SYNTHESIS; INTERMETALLIC COMPOUNDS; PRECIPITATION MECHANISM; TITANIUM ALUMINIDES; LIQUID AL; SOLID TI; TIAL3; COMPOSITE;
D O I
10.1016/j.jallcom.2008.07.035
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, a pre-heated compact of Ti/3Al powders was ignited and quenched by means of an improved combustion front quenching method (CFQM). The microstructural evolution in the quenched sample was observed with scanning electron microscopy (SEM) and analyzed with energy dispersive X-ray (EDX) spectrometry. In addition, the temperature-time profile was measured and the phase constituent of the final product was inspected by X-ray diffraction (XRD). Based on these experimental results, a dissolution-precipitation mechanism for the combustion reaction was proposed, and a model corresponding to the mechanism was drawn. Also, incompleteness of the synthesis was found, and it was because the reaction is a less-exothermic reaction. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:184 / 190
页数:7
相关论文
共 29 条
[1]   Effects of particle size of reactant on characteristics of combustion synthesis of TiC-Fe cermet [J].
Fan, QC ;
Chai, HF ;
Jin, ZH .
JOURNAL OF MATERIALS SCIENCE, 2002, 37 (11) :2251-2257
[2]   Dissolution-precipitation-substitution mechanism of self-propagating high-temperature synthesis of β-NiAl(Cu)/α(Cu,Ni) composite [J].
Fan, QC ;
Chai, HF ;
Jin, ZH .
INTERMETALLICS, 2002, 10 (06) :541-554
[3]   Dissolution-precipitation mechanism of self-propagating high-temperature synthesis of mononickel aluminide [J].
Fan, QC ;
Chai, HF ;
Jin, ZH .
INTERMETALLICS, 2001, 9 (07) :609-619
[4]   Dual-solution-precipitation mechanism of combustion synthesis of TiC-Fe cermet with fine Ti powder [J].
Fan, QC ;
Chai, HF ;
Jin, ZH .
JOURNAL OF MATERIALS SCIENCE, 2001, 36 (23) :5559-5563
[5]   SYNTHESIS, PROPERTIES AND APPLICATIONS OF TITANIUM ALUMINIDES [J].
FROES, FH ;
SURYANARAYANA, C ;
ELIEZER, D .
JOURNAL OF MATERIALS SCIENCE, 1992, 27 (19) :5113-5140
[6]   A new approach to the modeling of SHS reactions: Combustion synthesis of transition metal aluminides [J].
Gennari, Silvia ;
Tamburini, Umberto Anselmi ;
Maglia, Filippo ;
Spinolo, Giorgio ;
Munir, Zuhair A. .
ACTA MATERIALIA, 2006, 54 (09) :2343-2351
[7]   THERMODYNAMIC ASSESSMENT AND CALCULATION OF THE TI-AL SYSTEM [J].
KATTNER, UR ;
LIN, JC ;
CHANG, YA .
METALLURGICAL TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1992, 23 (08) :2081-2090
[8]  
Li ZQ, 2002, RARE METAL MAT ENG, V31
[9]   Combination of mechanochemical activation and self-propagating behaviour for the synthesis of Ti aluminides [J].
Medda, E ;
Delogu, F ;
Cao, G .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2003, 361 (1-2) :23-28
[10]   EFFECTS OF ALUMINUM CONCENTRATION AND COMPACT THICKNESS ON REACTION SYNTHESIS OF NI3AL-NIAL ALLOYS [J].
MIURA, S ;
LIU, CT .
INTERMETALLICS, 1994, 2 (04) :297-313