Different combinations of Fe3O4 microsphere, Polypyrrole and silver as core-shell nanocomposites for adsorption and photocatalytic application

被引:20
作者
Cheng, Yang [1 ,2 ]
Gao, Fang [1 ]
An, Liang [1 ]
Li, Xiaomin [1 ]
Wang, Guanghui [1 ]
机构
[1] Wuhan Univ Sci & Technol, Coll Chem Engn & Technol, Wuhan 430081, Peoples R China
[2] China Univ Geosci, Minist Educ, Engn Res Ctr Nanogeomat, Wuhan 430074, Peoples R China
关键词
Polypyrrole; Ferroferric oxide; Heterostructure; Adsorption; Photocatalysis; DOPED TIO2; HETEROSTRUCTURE NANOCRYSTALS; ANATASE TIO2; DEGRADATION; NANOFIBERS; NANOPARTICLES; COMPOSITES; PARTICLES; INTERFACE; NANOTUBES;
D O I
10.1016/j.apt.2014.05.013
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Several core-shell nanocomposites composed of Fe3O4 microspheres, Polypyrrole and silver were fabricated here by a series of wet chemical methods. The as-prepared nanocomposites were further used in adsorption and photodegradation of azo dyes. The chemical properties of the products were characterized by a series of techniques and equipment. The adsorption and photocatalytic activities of the obtained core-shell heterostructure were studied by controlled experiments. It was found that Fe3O4@PPy nanostructure exhibited the highest removal abilities towards organic dyes in aqueous solution among the as-prepared samples. The final removal ratio is 86.2% and 80.4% for Methyl Orange and Orange II aqueous solutions, respectively. Deposition of Ag nanoparticles was employed here to investigate the transportation and separation of photo-induced charges on the surface or interface of Fe3O4@PPy under UV illumination. (C) 2014 The Society of Powder Technology Japan. Published by Elsevier B. V. and The Society of Powder Technology Japan. All rights reserved.
引用
收藏
页码:1600 / 1607
页数:8
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