Synthetic studies on optically active Schiff-base ligands derived from condensation of 2-hydroxyacetophenone and chiral diamines

被引:73
作者
Gao, WT
Zheng, Z [1 ]
机构
[1] Jinzhou Normal Univ, Dept Chem & Environm Sci, Jinzhou 121003, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
关键词
Schiff-base; ligands; 2-hydroxyacetophenone; chiral diamines;
D O I
10.3390/70700511
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Three optically active Schiff-base ligands have been prepared by condensation of 2-hydroxyacetophenone with (IR,2R)-(-)-1,2-diaminocyclohexane, (1S,2S)-(-)1,2-diphenylethylenediamine or R-(+)-2,2'-diamino-1,1'-binaphthalene, respectively. The products have been characterized by their IR, H-1- and C-13-NMR spectra.
引用
收藏
页码:511 / 516
页数:6
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