Highly enantioselective synthesis of secondary alcohols using triphenylborane

被引：62

作者：

Rudolph, J ^{[1
]}

Schmidt, F ^{[1
]}

Bolm, C ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2004年 / 346卷 / 07期

关键词：

C-C bond formation; diarylmethanol; enantioselective catalysis; iron; triphenylborane; zinc organyls;

D O I：

10.1002/adsc.200404067

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Asymmetric phenyl transfer reactions with triphenylborane as aryl source and a ferrocene-based catalyst give secondary alcohols in high yields and excellent enantioselectivities.

引用

页码：867 / 872

页数：6

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