Highly enantioselective synthesis of secondary alcohols using triphenylborane

被引：62
|
作者：
Rudolph, J [1 ]
Schmidt, F [1 ]
Bolm, C [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2004年 / 346卷 / 07期
关键词：
C-C bond formation; diarylmethanol; enantioselective catalysis; iron; triphenylborane; zinc organyls;
D O I：
10.1002/adsc.200404067
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Asymmetric phenyl transfer reactions with triphenylborane as aryl source and a ferrocene-based catalyst give secondary alcohols in high yields and excellent enantioselectivities.
引用
收藏
页码：867 / 872
页数：6
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