Unusually high porosity in polymeric cluster cyanides:: the synthesis and crystal structure of(H3O)2Zn3 [Re6Se8(CN)6]2•20H2O

被引：0

作者：

Naumov, NG ^{[1
]}

Virovets, AV ^{[1
]}

Fedorov, VE ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 02期

关键词：

crystal structures; cluster compounds; rhenium complexes; cyanide complexes; porosity; polymers;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixing of aqueous solutions of the cluster anion [Re(6)Se(8)(CN)(6)](4-) and Zn(2+) in the presence of acetic acid (pH 3) leads to precipitation of (H(3)O)(2)Zn(3)[Re(6)Se(8)(CN)(6)](2). 20H(2)O having a three dimensional framework of {Zn(3)[Re(6)Se(8)(CN)(6)](2)}(2-) formed by Re-C=N-Zn covalent interactions. This framework occupies only 41.9% of the unit cell volume. The rest of the space is tilled by disordered water molecules and hydroxonium cations. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

引用

页码：71 / 72

页数：2

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